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    Chemistry

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    Also known as: Dl-thioctic acid, Alpha-lipoic acid, 1077-28-7, 5-(1,2-dithiolan-3-yl)pentanoic acid, Dl-alpha-lipoic acid, 1,2-dithiolane-3-pentanoic acid
    Molecular Formula
    C8H14O2S2
    Molecular Weight
    206.3  g/mol
    InChI Key
    AGBQKNBQESQNJD-UHFFFAOYSA-N
    FDA UNII
    73Y7P0K73Y
    Alpha Lipoic Acid
    An octanoic acid bridged with two sulfurs so that it is sometimes also called a pentanoic acid in some naming schemes. It is biosynthesized by cleavage of LINOLEIC ACID and is a coenzyme of oxoglutarate dehydrogenase (KETOGLUTARATE DEHYDROGENASE COMPLEX). It is used in DIETARY SUPPLEMENTS.
    1 2D Structure

    Alpha Lipoic Acid

    2 Identification
    2.1 Computed Descriptors
    2.1.1 IUPAC Name
    5-(dithiolan-3-yl)pentanoic acid
    2.1.2 InChI
    InChI=1S/C8H14O2S2/c9-8(10)4-2-1-3-7-5-6-11-12-7/h7H,1-6H2,(H,9,10)
    2.1.3 InChI Key
    AGBQKNBQESQNJD-UHFFFAOYSA-N
    2.1.4 Canonical SMILES
    C1CSSC1CCCCC(=O)O
    2.2 Other Identifiers
    2.2.1 UNII
    73Y7P0K73Y
    2.3 Synonyms
    2.3.1 MeSH Synonyms

    1. Acid, Alpha-lipoic

    2. Alpha Lipogamma

    3. Alpha Lipoic Acid

    4. Alpha Lipon Stada

    5. Alpha Liponaure Heumann

    6. Alpha Liponsaure Sofotec

    7. Alpha Liponsaure Von Ct

    8. Alpha Lippon Al

    9. Alpha Vibolex

    10. Alpha-lipogamma

    11. Alpha-lipoic Acid

    12. Alpha-lipon Stada

    13. Alpha-liponaure Heumann

    14. Alpha-liponsaure Sofotec

    15. Alpha-liponsaure Von Ct

    16. Alpha-lippon Al

    17. Alpha-vibolex

    18. Alphaflam

    19. Alphalipogamma

    20. Alphalipon Stada

    21. Alphaliponaure Heumann

    22. Alphaliponsaure Sofotec

    23. Alphaliponsaure Von Ct

    24. Alphalippon Al

    25. Alphavibolex

    26. Azulipont

    27. Biomo Lipon

    28. Biomo-lipon

    29. Biomolipon

    30. Duralipon

    31. Espa Lipon

    32. Espa-lipon

    33. Espalipon

    34. Fenint

    35. Injekt, Thiogamma

    36. Juthiac

    37. Lipoic Acid

    38. Liponsaure Ratiopharm

    39. Liponsaure-ratiopharm

    40. Liponsaureratiopharm

    41. Mtw Alphaliponsaure

    42. Mtw-alphaliponsaure

    43. Mtwalphaliponsaure

    44. Neurium

    45. Pleomix Alpha

    46. Pleomix Alpha N

    47. Pleomix-alpha

    48. Pleomix-alpha N

    49. Pleomixalpha

    50. Pleomixalpha N

    51. Thioctacid

    52. Thioctacide T

    53. Thiogamma Injekt

    54. Thiogamma Oral

    55. Tromlipon

    56. Verla Lipon

    57. Verla-lipon

    58. Verlalipon

    2.3.2 Depositor-Supplied Synonyms

    1. Dl-thioctic Acid

    2. Alpha-lipoic Acid

    3. 1077-28-7

    4. 5-(1,2-dithiolan-3-yl)pentanoic Acid

    5. Dl-alpha-lipoic Acid

    6. 1,2-dithiolane-3-pentanoic Acid

    7. Biletan

    8. Alpha Lipoic Acid

    9. 6,8-thioctic Acid

    10. Thioctacid

    11. Dl-6,8-thioctic Acid

    12. 6-thioctic Acid

    13. Lipothion

    14. 62-46-4

    15. 5-(dithiolan-3-yl)pentanoic Acid

    16. Dl-lipoic Acid

    17. Liposan

    18. Thioctsan

    19. Tioctacid

    20. Rac-lipoate

    21. 1,2-dithiolane-3-valeric Acid

    22. 6,8-dithiooctanoic Acid

    23. Alpha-liponsaeure

    24. Dl-6-thioctic Acid

    25. Thioctic Acid Dl-form

    26. 5-(1,2-dithiolan-3-yl)valeric Acid

    27. Alpha-liponic Acid

    28. Thioktsaeure

    29. Tioctidasi

    30. (rs)-lipoic Acid

    31. Espa-lipon

    32. 5-(dithiolan-3-yl)valeric Acid

    33. Acetate-replacing Factor

    34. 6,8-thiotic Acid

    35. Thioctansaeure

    36. 6-thiotic Acid

    37. .alpha.-lipoic Acid

    38. Dl-1,2-dithiolane 3-valeric Acid

    39. (+-)-lipoic Acid

    40. Thioctate

    41. Thioctic Acid [jan]

    42. Thioctsaeure

    43. Thiocacid

    44. Thioctan

    45. Liponic Acid

    46. Thiooctic Acid

    47. A-lipoic Acid

    48. Dl-.alpha.-lipoic Acid

    49. Acidum Thiocticum

    50. (+/-)-1,2-dithiolane-3-pentanoic Acid

    51. A-lipoicum Acidum

    52. Dl-1,2-dithiolane-3-valeric Acid

    53. Lipoate

    54. Mfcd00005474

    55. Nsc 90788

    56. Lipoic Acid, Alpha

    57. Lipoic Acid, Dl-

    58. Nsc 628502

    59. (+-)-1,2-dithiolane-3-pentanoic Acid

    60. .alpha.-liponic Acid

    61. Chebi:16494

    62. Dl-1,2-dithiolan-3-valeriansaeure

    63. (.+-.)-lipoic Acid

    64. Nsc-90788

    65. (rs)-.alpha.-lipoic Acid

    66. 5-[3-(1,2-dithiolanyl)]pentanoic Acid

    67. Chembl33864

    68. Tioctic Acid

    69. (.+-.)-.alpha.-lipoic Acid

    70. 73y7p0k73y

    71. 1,2-dithiolane-3-valeric Acid, (+-)-

    72. Nsc90788

    73. Nsc-628502

    74. Thioctic Acid (jan)

    75. Ncgc00016032-06

    76. Dsstox_cid_5508

    77. Protogen A

    78. (+/-)-alpha-lipoic Acid

    79. Dsstox_rid_77816

    80. Dsstox_gsid_25508

    81. (r)-(+)-alpha-lipoic Acid;r-(+)-thioctic Acid

    82. Thioktsaeure [german]

    83. Biomolipon

    84. Duralipon

    85. Alipure

    86. Alphalipogamma

    87. Thiotacid

    88. Biomo Lipon

    89. Espa Lipon

    90. Alpha Lipogamma

    91. Alpha-lipogamma

    92. Pyruvate Oxidation Factor

    93. Dl-thiocticacid

    94. Pleomix Alpha

    95. Thioctacide T

    96. Verla Lipon

    97. Alphalipon Stada

    98. Alpha Lippon Al

    99. Alpha-liponsaeure [german]

    100. Alpha Lipon Stada

    101. Alpha-lipon Stada

    102. 5-(1,2)dithiolan-3-yl-pentanoic Acid

    103. 5-[1,2]dithiolan-3-yl-pentanoic Acid

    104. Liponsaureratiopharm

    105. Alpha-lipon 300

    106. Smr000058198

    107. Cas-1077-28-7

    108. Liponsaure-ratiopharm

    109. (+-)-thioctic Acid

    110. 5-(3-(1,2-dithiolanyl))pentanoic Acid

    111. Alpha Liponsaure Von Ct

    112. Tioctidasi Acetate Replacing Factor

    113. Sr-01000737460

    114. Dl-6,8-dithiooctanoic Acid

    115. Lip(s2)

    116. (rs)-alpha-lipoic Acid

    117. Einecs 200-534-6

    118. Einecs 214-071-2

    119. (+-)-alpha-lipoic Acid

    120. Brn 0081853

    121. Brn 0122410

    122. Unii-73y7p0k73y

    123. Alpha Lipoic

    124. Alphalipoic-acid

    125. Dl-1,2-dithiolan-3-valeriansaeure [german]

    126. Thioctic Acid [inn:ban:jan]

    127. Hsdb 7818

    128. Alpha-lipoic-acid

    129. D,l-lipoic Acid

    130. Thiotomin (tn)

    131. Dl-a-lipoic Acid

    132. D,l-thioctic Acid

    133. Lipoic Acid (la)

    134. Alpha -lipoic Acid

    135. Rac ?-lipoic Acid

    136. (rs)-thioctic Acid

    137. Lipoic-acid

    138. ()-alpha-lipoic Acid

    139. Spectrum_001618

    140. 5-(1,2-dithiolan-3-yl)-pentanoate

    141. Thioctic Acid, Dl-form

    142. R-(+)-alpalipoic Acid

    143. 1,2-dithiolane-3-pentanoic Acid, (+-)-

    144. Spectrum2_001605

    145. Spectrum3_001188

    146. Spectrum4_000217

    147. Spectrum5_001298

    148. (s)-(-)-thiocticacid

    149. (+/-)-a-lipoic Acid

    150. Cid_864

    151. (.+-.)-thioctic Acid

    152. Lipoic Acid, Alpha [nf]

    153. Bmse000542

    154. Epitope Id:150922

    155. (+/-)-?-lipoic Acid

    156. (.+/-.)-lipoic Acid

    157. Thioctic Acid [mi]

    158. Schembl51065

    159. Bspbio_002835

    160. Dl-thioctic Acid (oxidized)

    161. Kbiogr_000853

    162. Kbioss_002098

    163. Thioctic Acid [hsdb]

    164. Thioctic Acid [inci]

    165. 5-19-07-00237 (beilstein Handbook Reference)

    166. Mls000069736

    167. Mls001332379

    168. Mls001332380

    169. Mls002153365

    170. Divk1c_000912

    171. Spectrum1503941

    172. Spbio_001609

    173. Thioctic Acid [mart.]

    174. Thioctic Acid [who-dd]

    175. Dtxsid7025508

    176. Bdbm10515

    177. Hms502n14

    178. Kbio1_000912

    179. Kbio2_002098

    180. Kbio2_004666

    181. Kbio2_007234

    182. Kbio3_002335

    183. A-lipoicum Acidum [hpus]

    184. Alpha Lipoic Acid [vandf]

    185. Alpha-lipoic Acid [vandf]

    186. Ninds_000912

    187. Thioctic Acid (alpha-lipoic Acid)

    188. Hms1922m22

    189. Hms3649h08

    190. Hms3885i16

    191. Pharmakon1600-01503941

    192. Thioctic Acid, (+/-)-

    193. Act14091

    194. Albb-030318

    195. Alpha Lipoic Acid [usp-rs]

    196. Bcp13221

    197. Bcp14048

    198. Bcp18944

    199. Hy-n0492

    200. Thioctic Acid Dl-form [mi]

    201. Tox21_110285

    202. Tox21_201808

    203. Tox21_303092

    204. Ac7875

    205. Bbl013878

    206. Ccg-39063

    207. Dl-1,2-dithiolane-3-pentanoic Acid

    208. Nsc628502

    209. Nsc758651

    210. S3996

    211. Stk801969

    212. Thioctic Acid [ep Monograph]

    213. ()-1,2-dithiolane-3-pentanoic Acid

    214. Akos000121582

    215. Akos016339634

    216. Tox21_110285_1

    217. Ab09328

    218. Am84329

    219. Cs-4370

    220. Ks-1322

    221. Nsc-758651

    222. Sb49517

    223. Idi1_000912

    224. Alpha Lipoic Acid [usp Impurity]

    225. Dl-thioctic Acid (oxidized) 25g

    226. Ncgc00016032-02

    227. Ncgc00016032-03

    228. Ncgc00016032-04

    229. Ncgc00016032-05

    230. Ncgc00016032-07

    231. Ncgc00016032-08

    232. Ncgc00016032-09

    233. Ncgc00016032-11

    234. Ncgc00016032-14

    235. Ncgc00090872-01

    236. Ncgc00090872-02

    237. Ncgc00090872-03

    238. Ncgc00090872-04

    239. Ncgc00090872-05

    240. Ncgc00256970-01

    241. Ncgc00259357-01

    242. (+/-)-alpha-lipoic Acid, >=98.0%

    243. .alpha.-lipoic Acid, (+/-)-

    244. Ac-22673

    245. Bp-31070

    246. Nci60_042014

    247. R)-(+)-

    248. A-lipoic Acid Ooethyaoethaea

    249. Sy010902

    250. (r)-(+)-(c) Paragraph Sign-lipoic Acid

    251. Sbi-0051871.p002

    252. 5-(1,2-dithiolan-3-yl)pentanoic Acid #

    253. Db-050522

    254. ( Inverted Exclamation Marka)-a-lipoic Acid

    255. 1,2-dithiolane-3-valeric Acid, (.+-.)-

    256. Ft-0622068

    257. Ft-0625429

    258. Ft-0670812

    259. Ft-0670813

    260. L0058

    261. 1,2-dithiolane-3-pentanoic Acid, (.+-.)-

    262. 1,2-dithiolane-3-valeric Acid, (.+/-.)-

    263. 1,2-dithiolane-3-pentanoic Acid, (.+/-.)-

    264. C00725

    265. D00086

    266. Ab00052393_09

    267. (+/-)?-?1,2-?dithiolane-?3-?pentanoic Acid

    268. A801751

    269. Q312229

    270. 1,2-dithiolane-3-pentanoic Acid, (+-)- (9ci)

    271. J-002007

    272. J-520421

    273. Sr-01000737460-2

    274. Sr-01000737460-6

    275. 5-((3rs)-1,2-dithiolan-3-yl)pentanoic Acid

    276. F2191-0208

    277. .delta.-(3-(1,2-dithiacyclopentyl))pentanoic Acid

    278. Thioctic Acid, European Pharmacopoeia (ep) Reference Standard

    279. (+/-)-alpha-lipoic Acid, Bioreagent, Cell Culture Tested, >=99%

    280. (+/-)-alpha-lipoic Acid, Synthetic, >=99% (titration), Powder

    281. Alpha Lipoic Acid, United States Pharmacopeia (usp) Reference Standard

    282. (r)-(+)-1,2-dithiolane-3-pentanoic Acid; R-(+)-thioctic Acid; R-(+)-alpha-lipoic Acid

    283. Afae'a Centa' Nota Inverted Exclamation Markafasa'a

    284. Afae'adaggeratrade Mark?-lipoic Acid

    285. Thioctic Acid Containing Impurity B, European Pharmacopoeia (ep) Reference Standard

    286. Thioctic Acid For System Suitability, European Pharmacopoeia (ep) Reference Standard

    287. Thioctic Acid;1,2-dithiolane-3-pentanoic Acid;5-(1,2-dithiolan-3-yl)valeric Acid

    2.3.3 Other Synonyms

    1. 1200-22-2

    2. (r)-lipoic Acid

    3. Heparlipon

    4. Lipoec

    5. Tioctic Acid

    2.4 Create Date
    2004-09-16
    3 Chemical and Physical Properties
    Molecular Weight 206.3 g/mol
    Molecular Formula C8H14O2S2
    XLogP31.7
    Hydrogen Bond Donor Count1
    Hydrogen Bond Acceptor Count4
    Rotatable Bond Count5
    Exact Mass206.04352203 g/mol
    Monoisotopic Mass206.04352203 g/mol
    Topological Polar Surface Area87.9 Ų
    Heavy Atom Count12
    Formal Charge0
    Complexity150
    Isotope Atom Count0
    Defined Atom Stereocenter Count0
    Undefined Atom Stereocenter Count1
    Defined Bond Stereocenter Count0
    Undefined Bond Stereocenter Count0
    Covalently Bonded Unit Count1
    4 Drug and Medication Information
    4.1 Therapeutic Uses

    /EXPERIMENTAL THERAPY/ The aim of this trial was to evaluate the effects of alpha-lipoic acid (ALA) on positive sensory symptoms and neuropathic deficits in diabetic patients with distal symmetric polyneuropathy (DSP). In this multicenter, randomized, double-blind, placebo-controlled trial, 181 diabetic patients in Russia and Israel received once-daily oral doses of 600 mg (n = 45) (ALA600), 1,200 mg (n = 47) (ALA1200), and 1,800 mg (ALA1800) of ALA (n = 46) or placebo (n = 43) for 5 weeks after a 1-week placebo run-in period. The primary outcome measure was the change from baseline of the Total Symptom Score (TSS), including stabbing pain, burning pain, paresthesia, and asleep numbness of the feet. Secondary end points included individual symptoms of TSS, Neuropathy Symptoms and Change (NSC) score, Neuropathy Impairment Score (NIS), and patients' global assessment of efficacy. Mean TSS did not differ significantly at baseline among the treatment groups and on average decreased by 4.9 points (51%) in ALA600, 4.5 (48%) in ALA1200, and 4.7 (52%) in ALA1800 compared with 2.9 points (32%) in the placebo group (all P < 0.05 vs. placebo). The corresponding response rates (> or = 50% reduction in TSS) were 62, 50, 56, and 26%, respectively. Significant improvements favoring all three ALA groups were also noted for stabbing and burning pain, the NSC score, and the patients' global assessment of efficacy. The NIS was numerically reduced. Safety analysis showed a dose-dependent increase in nausea, vomiting, and vertigo. CONCLUSIONS: Oral treatment with ALA for 5 weeks improved neuropathic symptoms and deficits in patients with DSP. An oral dose of 600 mg once daily appears to provide the optimum risk-to-benefit ratio.

    PMID:17065669 Ziegler D E et al; Diabetes Care 29 (11): 2365-70 (2006)

    /EXPERIMENTAL THERAPY/ Mitochondria produce reactive oxygen species that may contribute to vascular dysfunction. alpha-Lipoic acid and acetyl-L-carnitine reduce oxidative stress and improve mitochondrial function. In a double-blind crossover study, the authors examined the effects of combined alpha-lipoic acid/acetyl-L-carnitine treatment and placebo (8 weeks per treatment) on vasodilator function and blood pressure in 36 subjects with coronary artery disease. Active treatment increased brachial artery diameter by 2.3% (P=.008), consistent with reduced arterial tone. Active treatment tended to decrease systolic blood pressure for the whole group (P=.07) and had a significant effect in the subgroup with blood pressure above the median (151+/-20 to 142+/-18 mm Hg; P=.03) and in the subgroup with the metabolic syndrome (139+/-21 to 130+/-18 mm Hg; P=.03). Thus, mitochondrial dysfunction may contribute to the regulation of blood pressure and vascular tone....

    PMID:17396066 Full text: https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2734271 McMackin CJ et al; J Clin Hypertens (Greenwich) 9 (4): 249-55 (2007)

    /EXPERIMENTAL THERAPY/ Lipoic acid is an antioxidant that suppresses and treats an animal model of multiple sclerosis, experimental autoimmune encephalomyelitis. The purpose of this study was to determine the pharmacokinetics (PK), tolerability and effects on matrix metalloproteinase-9 (MMP-9) and soluble intercellular adhesion molecule-1 (sICAMP-1) of oral lipoic acid in patients with multiple sclerosis. Thirty-seven MS subjects were randomly assigned to one of four groups: placebo, lipoic acid 600 mg twice a day, lipoic acid 1200 mg once a day and lipoic acid 1200 mg twice a day. Subjects took study capsules for 14 days. ... Subjects taking 1200 mg lipoic acid had substantially higher peak serum lipoic acid levels than those taking 600 mg and that peak levels varied considerably among subjects. We also found a significant negative correlation between peak serum lipoic acid levels and mean changes in serum MMP-9 levels (T = -0.263, P =0.04). There was a significant dose response relationship between lipoic acid and mean change in serum sICAM-1 levels (P =0.03). ... Oral lipoic acid is generally well tolerated and appears capable of reducing serum MMP-9 and sICAM-1 levels. Lipoic acid may prove useful in treating MS by inhibiting MMP-9 activity and interfering with T-cell migration into the CNS.

    PMID:15794388 Yadav V et al; Mult Scler 11 (2): 159-65 (2005)

    /EXPERIMENTAL THERAPY/ Mitochondrial dysfunction and oxidative damage are highly involved in the pathogenesis of Parkinson's disease. Some mitochondrial antioxidants/nutrients that can improve mitochondrial function and/or attenuate oxidative damage have been implicated in Parkinson's disease therapy. However, few studies have evaluated the preventative effects of a combination of mitochondrial antioxidants/nutrients against Parkinson's disease, and even fewer have sought to optimize the doses of the combined agents. The present study examined the preventative effects of two mitochondrial antioxidant/nutrients, R-alpha-lipoic acid (LA) and acetyl-L-carnitine (ALC), in a chronic rotenone-induced cellular model of Parkinson's disease. We demonstrated that 4-week pretreatment with LA and/or ALC effectively protected SK-N-MC human neuroblastoma cells against rotenone-induced mitochondrial dysfunction, oxidative damage, and accumulation of alpha-synuclein and ubiquitin. Most notably, we found that when combined, LA and ALC worked at 100 to 1000 fold lower concentrations than they did individually. We also found that pretreatment with combined LA and ALC increased mitochondrial biogenesis and decreased production of reactive oxygen species through the upregulation of the peroxisome proliferator-activated receptor-gamma coactivator 1alpha as a possible underlying mechanism. This study provides important evidence that combining mitochondrial antioxidant/nutrients at optimal doses might be an effective and safe prevention strategy for Parkinson's disease. /R-alpha-lipoic acid/

    PMID:18624765 Zhang H et al; J Cell Mol Med. 2008 Jun 20. (Epub ahead of print)

    For more Therapeutic Uses (Complete) data for alpha-Lipoic acid (11 total), please visit the HSDB record page.

    4.2 Drug Warning

    Those with diabetes and problems with glucose intolerance are cautioned that supplemental alpha-lipoic acid may lower blood glucose levels. Blood glucose should be monitored and antidiabetic drug dose adjusted, if necessary, to avoid possible hypoglycemia.

    PDR for Nutritional Supplements 2nd ed. Thomson Reuters, Montvale, NJ 2008, p. 28

    Because of lack of long-term safety data, alpha-lipoic acid should be avoided by pregnant and nursing mothers.

    PDR for Nutritional Supplements 2nd ed. Thomson Reuters, Montvale, NJ 2008, p. 28

    5 Pharmacology and Biochemistry
    5.1 MeSH Pharmacological Classification

    Antioxidants

    Naturally occurring or synthetic substances that inhibit or retard oxidation reactions. They counteract the damaging effects of oxidation in animal tissues. (See all compounds classified as Antioxidants.)

    Vitamin B Complex

    A group of water-soluble vitamins, some of which are COENZYMES. (See all compounds classified as Vitamin B Complex.)

    5.2 ATC Code

    A - Alimentary tract and metabolism

    A16 - Other alimentary tract and metabolism products

    A16A - Other alimentary tract and metabolism products

    A16AX - Various alimentary tract and metabolism products

    A16AX01 - Thioctic acid

    5.3 Absorption, Distribution and Excretion

    To determine the concentration of alpha-lipoic acid in the aqueous humour and investigate if its topical instillation can increase quantities. Methods: Seventy patients selected to undergo cataract surgery were randomly divided into two groups. Group 1 was used as a control group; for the patients in Group 2, a single instillation of alpha-lipoic acid eye drops (1%) was administered. Immediately before surgery an aliquot of 40-120 microL of aqueous humour was aspirated. The individual aspirations were combined to constitute pools representing time intervals with respect to administration. The levels of alpha-lipoic acid in the aqueous humour were measured using gas chromatography/mass-spectrometry. Pool 0 was created by combining the samples of aqueous humour obtained from the patients in Group 1, the control group, and the level of alpha-lipoic acid was 27.5 + 2.6 ng/mL; in the other pools the time interval between the administration of the eye drops and sampling was respectively 23 minutes, 53 minutes, 72 minutes, 93 minutes and 114 minutes, and the level of alpha-lipoic acid was 33.0 + 10.8 ng/mL; 52.0 + 2.5 ng/mL; 86.7 + 2.5 ng/mL; 91.2 + 2.5 ng/mL; 80.3 + 2.5 ng/mL. /The/ study demonstrates the presence of alpha-lipoic acid in the aqueous humour and indicates that its concentration increases after it is administered in the form of eye drops, reaching maximum values after around 93 minutes. The concentrations that are achieved in the anterior chamber allow us to theorise the possibility of exploiting the antioxidant properties of alpha-lipoic acid.

    PMID:20456443 Cagini C et al; Clin Experiment Ophthalmol 38 (6): 572-6 (2010)

    R(+)-alpha-lipoic acid is a natural occurring compound that acts as an essential cofactor for certain dehydrogenase complexes. The redox couple alpha-lipoic acid/dihydrolipoic acid possesses potent antioxidant activity. Exogenous racemic alpha-lipoic acid orally administered for the symptomatic treatment of diabetic polyneuropathy is readily and nearly completely absorbed, with a limited absolute bioavailability of about 30% caused by high hepatic extraction. Although the pharmacokinetics of the parent drug have been well characterized in humans, relatively little is known regarding the excretion of alpha-lipoic acid and the pharmacokinetics of any metabolites in humans. In the present study, plasma concentration-time courses, urinary excreted amounts, and pharmacokinetic parameters of alpha-lipoic acid metabolites were evaluated in 9 healthy volunteers after multiple once-daily oral administration of 600 mg racemic alpha-lipoic acid. The primary metabolic pathways of alpha-lipoic acid in man, S-methylation and beta-oxidation, were quantitatively confirmed by an HPLC-electrochemical assay newly established prior to the beginning of this study. Major circulating metabolites were the S-methylated beta-oxidation products 4,6-bismethylthio-hexanoic acid and 2,4-bismethylthio-butanoic acid, whereas its conjugated forms accounted for the major portion excreted in urine. There was no statistically significant difference in the pharmacokinetic parameters Cmax, AUC, and tmax between day 1 and day 4. Despite the prolonged half-lives of the major metabolites compared to the parent drug, no evidence of accumulation was found. Mean values of 12.4% of the administered dose were recovered in the urine after 24 hours as the sum of alpha-lipoic acid and its metabolites. The results of the present study revealed that urinary excretion of alpha-lipoic acid and five of its main metabolites does not play a significant role in the elimination of alpha-lipoic acid. Therefore, biliary excretion, further electrochemically inactive degradation products, and complete utilization of alpha-lipoic acid as a primary substrate in the endogenous metabolism should be considered.

    PMID:14551180 Teichert J et al; J Clin Pharmacol 43 (11):1257-67 (2003)

    In an open-label, parallel-group study involving 16 patients (8 with severely reduced renal function, 8 with end-stage renal disease needing hemodialysis), the effect of renal function on the pharmacokinetics, metabolism, and safety `of alpha-lipoic acid (thioctic acid) was evaluated by comparing the pharmacokinetic parameters with those of a reference group of 8 healthy subjects. Alpha-lipoic acid 600 mg was administered orally once daily for 4 days, and the pharmacokinetic parameters were measured on days 1 and 4. The mean percentage of the administered dose excreted in urine as parent compound was 0.2 and 0.05 in healthy subjects and subjects with severely reduced renal function, respectively. Assuming a bioavailability of 30%, this represents 0.67% and 0.17% of the bioavailable amount of alpha-lipoic acid, respectively. The percentage of total urinary recovered amounts of alpha-lipoic acid and 5 of its metabolites was 12.0 on both days. The respective values for patients with severe kidney damage were 5.2% (day 1) and 6.4% (day 4). The total percentage of the administered dose removed by hemodialysis was 4.0 in patients with end-stage renal disease. Renal clearance of alpha-lipoic acid and its major metabolites, 6,8-bismethylthio-octanoic acid, 4,6-bismethylthio-hexanoic acid and 2,4-bismethylthio-butanoic acid, were significantly decreased in subjects with kidney damage compared to the reference group. Apparent total clearance of alpha-lipoic acid was poorly correlated with creatinine clearance. There is strong evidence that alpha-lipoic acid is mainly excreted by nonrenal mechanism or further degraded to smaller units in the catabolic process. The significantly increased area under the curve values of 4,6-bismethylthio-hexanoic acid and half-lives of 2,4-bismethylthio-butanoic acid on both days in patients with severely reduced function and end-stage renal disease were not considered to be clinically relevant. Although trough levels of both metabolites tend to increase slightly in these subjects, no accumulation effects were detected. We conclude that the pharmacokinetics of alpha-lipoic acid are not influenced by creatinine clearance and are unaffected in subjects with severely reduced kidney function or end-stage renal disease. Hemodialysis did not significantly contribute to the clearance of alpha-lipoic acid. Hence, dose adjustment of alpha-lipoic acid is not necessary in patients with renal dysfunction.

    PMID:15703366 Teichert J et al; J Clin Pharmacol 45 (3): 313-28 (2005)

    Alpha-lipoic aicd is absorbed from the small intestine and distributed to the liver via the portal circulation and to various tissues in the body via the systemic circulation.The natural R-enantiomer is more readily absorbed than the L-enantiomer and is the more active form. Alpha-lipoic acid readily crosses the blood-brain barrier. It is found, after its distribution to the various body tissues, intracellularly, intramitochondrialy and extracellularly.

    PDR for Nutritional Supplements 2nd ed. Thomson Reuters, Montvale, NJ 2008, p. 26

    5.4 Metabolism/Metabolites

    Alpha-lipoic acid is metabolized to its reduced form, dihydrolipoic acid by mitochondrial lipoamide dehydrogenase. Dihydroipoic acid, together with lipoic acid, form a redox couple. It is also metabolized to lipoamide, which functions as the lipoic acid cofactor in the multienzyme complexes that catalyze the oxidative decarboxylations of pyruvate and alpha-ketoglutarate. Alpha-lipoic acid may be metabolized to dithiol octanoic acid, which can undergo catabolism.

    PDR for Nutritional Supplements 2nd ed. Thomson Reuters, Montvale, NJ 2008, p. 26

    The excretion and biotransformation of rac-alpha-lipoic acid (LA), which is used for the symptomatic treatment of diabetic polyneuropathy, were investigated following single oral dosing of [(14)C]LA to mice (30 mg/kg), rats (30 mg/kg), dogs (10 mg/kg), and unlabeled LA to humans (600 mg). More than 80% of the radioactivity given was renally excreted. Metabolite profiles obtained by radiometric high-performance liquid chromatography revealed that LA was extensively metabolized irrespective of the species. Based on a new on-line liquid chromatography/tandem mass spectroscopy assay developed for negative ions, LA and a total of 12 metabolites were identified. Mitochondrial beta-oxidation played the paramount role in the metabolism of LA. Simultaneously, the circulating metabolites were subjected to reduction of the 1,2-dithiolane ring and subsequent S-methylation. In addition, evidence is given for the first time that the methyl sulfides formed were partly oxidized to give sulfoxides, predominantly in dogs. The disulfoxide of 2,4-bismethylmercapto-butanoic acid, the most polar metabolite identified, was the major metabolite in dogs. Furthermore, new data are presented that suggest conjugation with glycine occurred as a separate metabolic pathway in competition with beta-oxidation, predominantly in mice.

    PMID:11353754 Schupke H et al; Drug Metab Dispos 29 (6): 855-62 (2001)

    5.5 Mechanism of Action

    Alpha-lipoic acid (LA) shows a protective effect on oxidative stress-induced apoptosis while it induces apoptosis in various cancer cells. Intracellular Ca(2+) plays a central role in triggering apoptotic pathways. In the present study, we aim to investigate whether LA induces apoptosis in lung cancer cells and whether Ca(2+) is involved in LA-induced apoptosis. We found that LA decreased cell viability and increased DNA fragmentation of the cells. LA activated the caspase-independent pathway, determined by upregulation of poly(ADP-ribose) polymerase (PARP) and increased the nuclear level of apoptosis-inducing factor and caspase-dependent apoptotic pathway, determined by increased levels of cytochrome c and PARP-1 cleavage product. LA-induced apoptotic alterations were inhibited in the cells treated with Ca(2+) chelator BAPTA-AM. In conclusion, LA induces apoptosis through caspase-independent and caspase-dependent pathways, which is mediated by intracellular Ca(2+).

    PMID:19723049 Choi SY et al; Ann N Y Acad Sc 1171: 149-55 (2009)

    Alpha-lipoic acid is known to increase insulin sensitivity in vivo and to stimulate glucose uptake into adipose and muscle cells in vitro. In this study, alpha-lipoic acid was demonstrated to stimulate the autophosphorylation of insulin receptor and glucose uptake into 3T3-L1 adipocytes by reducing the thiol reactivity of intracellular proteins. To elucidate mechanism of this effect, role of protein thiol groups and H(2)O(2) in insulin receptor autophosphorylation and glucose uptake was investigated in 3T3-L1 adipocytes following stimulation with alpha-lipoic acid. Alpha-lipoic acid or insulin treatment of adipocytes increased intracellular level of oxidants, decreased thiol reactivity of the insulin receptor beta-subunit, increased tyrosine phosphorylation of the insulin receptor, and enhanced glucose uptake. Alpha-lipoic acid or insulin-stimulated glucose uptake was inhibited (i) by alkylation of intracellular, but not extracellular, thiol groups downstream of insulin receptor activation, and (ii) by diphenylene iodonium at the level of the insulin receptor autophosphorylation. alpha-Lipoic acid also inhibited protein tyrosine phosphatase activity and decreased thiol reactivity of protein tyrosine phosphatase 1B. These findings indicate that oxidants produced by alpha-lipoic acid or insulin are involved in activation of insulin receptor and in inactivation of protein tyrosine phosphatases, which eventually result in elevated glucose uptake into 3T3-L1 adipocytes.

    PMID:12948866 Cho KJ et al; Biochem Pharmacol 66 (5): 849-58 (2003)

    Reactive oxygen (ROS) and nitrogen oxide (RNOS) species are produced as by-products of oxidative metabolism. A major function for ROS and RNOS is immunological host defense. Recent evidence indicate that ROS and RNOS may also function as signaling molecules. However, high levels of ROS and RNOS have been considered to potentially damage cellular macromolecules and have been implicated in the pathogenesis and progression of various chronic diseases. alpha-Lipoic acid and dihydrolipoic acid exhibit direct free radical scavenging properties and as a redox couple, with a low redox potential of -0.32 V, is a strong reductant. Several studies provided evidence that alpha-lipoic acid supplementation decreases oxidative stress and restores reduced levels of other antioxidants in vivo. However, there is also evidence indicating that alpha-lipoic acid and dihydrolipoic acid may exert prooxidant properties in vitro. alpha-Lipoic acid and dihydrolipoic acid were shown to promote the mitochondrial permeability transition in permeabilized hepatocytes and isolated rat liver mitochondria. Dihydrolipoic acid also stimulated superoxide anion production in rat liver mitochondria and submitochondrial particles. alpha-Lipoic acid was recently shown to stimulate glucose uptake into 3T3-L1 adipocytes by increasing intracellular oxidant levels and/or facilitating insulin receptor autophosphorylation presumably by oxidation of critical thiol groups present in the insulin receptor beta-subunit. Whether alpha-lipoic acid and/or dihydrolipoic acid-induced oxidative protein modifications contribute to their versatile effects observed in vivo warrants further investigation.

    PMID:12127266 Moini H et al; Toxicol Appl Pharmacol 182 (1): 84-90 (2002)

    This study investigated the effect of alpha-lipoic acid (ALA) in concentration range 0.7-5.0 mM on the intracellular level of reduced glutathione, the cell cycle phase distribution, the structure of microfilaments and microtubules of normal (3T3) and transformed (3T3-SV40) fibroblasts. We obtained that ALA increased the glutathione content in transformed cells, but did not change its level in normal cells, induced cell cycle arrest of 3T3 cells (but not 3T3-SV40 cells), and disrupted actin microfilaments in cells of both lines. The effect of ALA was compared with N-acetylcysteine (NAC) action. The whole complex of findings allows us to affirm that each of these antioxidants acts on its own target molecules in normal and transformed cells and activates different signal and metabolic pathways in these cells. But at the same time the intermediate steps of ALA and NAC action can be common (alteration of the intracellular level of glutathione, reorganization of actin cytoskeleton, etc.).

    PMID:20141032 Vakhromova EA et al; Tsitologiia 51 (12): 971-7 (2009)

    For more Mechanism of Action (Complete) data for alpha-Lipoic acid (7 total), please visit the HSDB record page.

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      CEP 2008-119 - Rev 02
      Valid
      Chemical
      2024-09-25
      1648
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      04

      SINOPHARM WEIQIDA PHARMACEUTICAL CO...

      China
      AES 2024
      Not Confirmed
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      JDMF

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      01

      Tateyama Chemical Co., Ltd.

      Japan
      AES 2024
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      Tateyama Chemical Co., Ltd.

      Japan
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      AES 2024
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      Extra-official regulations Thioctic acid amide (for manufacturing only)

      Registration Number : 227MF10162

      Registrant's Address : 1133 Oe, Imizu City, Toyama Prefecture

      Initial Date of Registration : 2015-06-18

      Latest Date of Registration : 2015-06-18

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      02

      Tateyama Chemical Co., Ltd.

      Japan
      AES 2024
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      Tateyama Chemical Co., Ltd.

      Japan
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      Extra-official regulations Thioctic acid amide (for manufacturing only)

      Registration Number : 217MF10340

      Registrant's Address : 1133 Oe, Imizu City, Toyama Prefecture

      Initial Date of Registration : 2005-07-21

      Latest Date of Registration : 2010-02-16

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      03

      Tateyama Chemical Co., Ltd.

      Japan
      AES 2024
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      Tateyama Chemical Co., Ltd.

      Japan
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      Thioctic acid

      Registration Number : 222MF10195

      Registrant's Address : 1133 Oe, Imizu City, Toyama Prefecture

      Initial Date of Registration : 2010-07-13

      Latest Date of Registration : 2010-07-13

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      04

      Tateyama Chemical Co., Ltd.

      Japan
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      Tateyama Chemical Co., Ltd.

      Japan
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      Thioctic acid

      Registration Number : 217MF10341

      Registrant's Address : 1133 Oe, Imizu City, Toyama Prefecture

      Initial Date of Registration : 2005-07-21

      Latest Date of Registration : 2009-09-28

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      KDMF

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      Ami Lifesciences Private Limited

      India
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      Altioctane tromethamine salt

      Registrant Name : Aging Life Science Co., Ltd.

      Registration Date : 2024-01-19

      Registration Number : 20240119-166-I-668-18

      Manufacturer Name : Ami Lifesciences Private Lim...

      Manufacturer Address : Block No. 82/B, ECP Road At & Post. Karakhadi, Tal-Padra, City : Karakhadi-391450, Di...

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      02

      Ami Lifesciences Private Limited

      India
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      Virtual BoothAMI Lifesciences is Driven by Chemistry. Powered by People.

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      Altioctane tromethamine salt

      Registrant Name : Pharmapia Co., Ltd.

      Registration Date : 2024-05-01

      Registration Number : 20240119-166-I-668-18(1)

      Manufacturer Name : Ami Lifesciences Private Lim...

      Manufacturer Address : Block No. 82/B, ECP Road At & Post. Karakhadi, Tal-Padra, City : Karakhadi-391450, Di...

      AMI Lifesciences

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      03

      Hanseo Chem

      South Korea
      AES 2024
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      Hanseo Chem

      South Korea
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      AES 2024
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      Altioctane tromethamine salt

      Registrant Name : Hanseochem Co., Ltd.

      Registration Date : 2017-07-28

      Registration Number : 20170728-166-I-532-11

      Manufacturer Name : Hanseochem Co., Ltd. @ [Manu...

      Manufacturer Address : 41@No. 13, Dongzhou Road, Bixi Subdistrict, Changshu City, Suzhou City, Jiangsu Provi...

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      Kinsy SL

      Spain
      AES 2024
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      Kinsy SL

      Spain
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      thioctic acid

      Registrant Name : Aging Life Science Co., Ltd.

      Registration Date : 2017-09-07

      Registration Number : 20170907-166-I-526-12

      Manufacturer Name : Kinsy SL

      Manufacturer Address : Avda. Europa s/n, Parque Industrial de Alhama, Alhama de Murcia 30840, Spain

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      05

      Korea Biochem Pharm

      South Korea
      AES 2024
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      Korea Biochem Pharm

      South Korea
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      Thioctate tromethamine salt

      Registrant Name : Korea Biochem Pharmaceutical Co., Ltd.

      Registration Date : 2020-07-22

      Registration Number : 20200722-166-I-609-14

      Manufacturer Name : Korea Biochem Pharmaceutical...

      Manufacturer Address : 204 Sandan-gil, Jeonui-myeon, Sejong Special Self-Governing City @ [Tioctane Manufact...

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      06

      Korea Biochem Pharm

      South Korea
      AES 2024
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      Korea Biochem Pharm

      South Korea
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      Altioctic acid

      Registrant Name : Korea Biochem Pharmaceutical Co., Ltd.

      Registration Date : 2017-12-15

      Registration Number : 20171215-166-I-541-13

      Manufacturer Name : Korea Biochem Pharmaceutical...

      Manufacturer Address : 204 Sandan-gil, Jeonui-myeon, Sejong Special Self-Governing City @Haikou Integrated F...

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      07

      Kukjeon Pharmaceutical

      South Korea
      AES 2024
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      Kukjeon Pharmaceutical

      South Korea
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      AES 2024
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      Altioctane tromethamine salt

      Registrant Name : Kukjeon Pharmaceutical Co., Ltd.

      Registration Date : 2017-05-29

      Registration Number : 20170529-166-I-533-10

      Manufacturer Name : Kookjeon Pharmaceutical Co.,...

      Manufacturer Address : 8, Balan Industrial Complex-ro, Hyangnam-eup, Hwaseong-si, Gyeonggi-do @ [Product man...

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      08

      Shandong Qidu Pharmaceutical

      China
      AES 2024
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      Shandong Qidu Pharmaceutical

      China
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      AES 2024
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      thioctic acid

      Registrant Name : Seongun Pharmacopia Co., Ltd.

      Registration Date : 2023-03-20

      Registration Number : 20230320-166-I-657-17

      Manufacturer Name : Shandong Qidu Pharmaceutical...

      Manufacturer Address : No.17, Hongda Road, Linzi District, Zibo City, Shandong Province, PRChina

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      09

      Shandong Qidu Pharmaceutical

      China
      AES 2024
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      Shandong Qidu Pharmaceutical

      China
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      AES 2024
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      thioctic acid

      Registrant Name : Toru Corporation

      Registration Date : 2023-09-25

      Registration Number : 20230320-166-I-657-17(1)

      Manufacturer Name : Shandong Qidu Pharmaceutical...

      Manufacturer Address : No.17, Hongda Road, Linzi District, Zibo City, Shandong Province, PRChina

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      10

      Shandong Qidu Pharmaceutical

      China
      AES 2024
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      Shandong Qidu Pharmaceutical

      China
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      AES 2024
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      thioctic acid

      Registrant Name : Otran Pharm Korea Co., Ltd.

      Registration Date : 2023-12-26

      Registration Number : 20230320-166-I-657-17(2)

      Manufacturer Name : Shandong Qidu Pharmaceutical...

      Manufacturer Address : No.17, Hongda Road, Linzi District, Zibo City, Shandong Province, PRChina

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      NDC API

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      01

      Olon S.p.A.

      Italy
      AES 2024
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      Olon S.p.A.

      Italy
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      AES 2024
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      .ALPHA.-LIPOIC ACID

      NDC Package Code : 17337-0402

      Start Marketing Date : 2017-03-09

      End Marketing Date : 2025-12-31

      Dosage Form (Strength) : POWDER (1kg/kg)

      Marketing Category : BULK INGREDIENT

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      02

      Olon SpA

      Italy
      AES 2024
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      Olon SpA

      Italy
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      AES 2024
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      .ALPHA.-LIPOIC ACID

      NDC Package Code : 17337-0054

      Start Marketing Date : 2013-09-27

      End Marketing Date : 2024-12-31

      Dosage Form (Strength) : POWDER (1kg/kg)

      Marketing Category : BULK INGREDIENT

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      03

      Professional Compounding Centers of...

      United Kingdom
      AES 2024
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      Professional Compounding Centers of...

      United Kingdom
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      THIOCTIC ACID

      NDC Package Code : 51927-5064

      Start Marketing Date : 2019-07-18

      End Marketing Date : 2024-12-31

      Dosage Form (Strength) : POWDER (1kg/kg)

      Marketing Category : BULK INGREDIENT FOR HUMAN P...

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      Listed Suppliers

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      01

      Basic Nutrition

      China
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      Medlab Asia & Asia Health
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      Virtual BoothBasic Nutrition, your expert for sourcing from China, India and Europe.

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      alpha-Lipoic Acid

      About the Company : As an ISO9001, ISO22000 certificated supplier, Basic Nutrition supply high-quality ingredients for nutraceuticals. We can offer a range of products from small to large quantites: h...

      As an ISO9001, ISO22000 certificated supplier, Basic Nutrition supply high-quality ingredients for nutraceuticals. We can offer a range of products from small to large quantites: herbal extract, amino acid, vitamin, etc. Featured products: cranberry extract, rhidiola extract, Q10, hyaluronic acid, cysteine (non-animals), glutathoninr, orgaic products like organic spirulina, organic red yeast rice powder, etc.
      Basic Nutrition Company Banner

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      02

      Tagoor Laboratories

      India
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      Medlab Asia & Asia Health
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      Virtual BoothTagoor's product development expertise, backed by our comprehensive understanding of the processes, helps us offer high-quality APIs.

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      Alpha Lipoic Acid

      About the Company : Tagoor Laboratories, established in 2018, is a part of the Tagoor Group. It specializes in providing APIs, advanced intermediates and key starting materials for critical and high-g...

      Tagoor Laboratories, established in 2018, is a part of the Tagoor Group. It specializes in providing APIs, advanced intermediates and key starting materials for critical and high-growth therapeutic areas, with an emphasis on affordability, quality and timely delivery. It also provides end-to-end CDMO services. Headquartered in Hyderabad, Tagoor Labs is a fast-growing Indian pharma company that serves both branded and generic companies worldwide. The company’s organizational function includes R&D, supply chain, manufacturing, quality testing, quality assurance, regulatory affairs, marketing & sales, and packaging & warehousing departments.
      Tagoor Laboratories

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      03

      LGM Pharma

      U.S.A
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      Virtual BoothLGM Pharma accelerates & optimizes the new product pathway from early development through commercialization.

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      Alpha Lipoic Acid

      About the Company : LGM Pharma is a global leader in sourcing hard-to-find APIs and intermediates for the pharmaceutical and biotech industries. LGM is also a full service CDMO providing formulation, ...

      LGM Pharma is a global leader in sourcing hard-to-find APIs and intermediates for the pharmaceutical and biotech industries. LGM is also a full service CDMO providing formulation, analytical method development and testing, and commercial manufacturing. LGM Pharma offers custom API synthesis, analytical development, and regulatory services. With a network of over 300 accredited CGMP manufacturing partners, LGM provides unparalleled supply chain security. And, with over 100,000 square feet of FDA-inspected cGMP manufacturing and warehouse capacity, LGM Pharma provides a one-stop solution for solid dose, powder, semi-solid and liquid drugs.
      LGM Pharma CB

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      04

      Rochem International Inc

      U.S.A
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      Virtual BoothRochem, your partner in developing, sourcing, and supplying pharmaceutical & animal health ingredients of Chinese origin.

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      Alpha Lipoic Acid

      About the Company : Established in 1994, Rochem is a distributor of pharmaceutical, food, nutritional and animal health ingredients to some of the largest companies in the world. It sources high-quali...

      Established in 1994, Rochem is a distributor of pharmaceutical, food, nutritional and animal health ingredients to some of the largest companies in the world. It sources high-quality ingredients manufactured in China. Headquartered in the Hauppauge, New York, Rochem has 16 offices spread across the globe to cater to the needs of its customers. Rochem’s operations are fully cGMP compliant and has been audited by the USFDA as well as several multinational organizations. It also trains and audits its partners to ensure all of their technologies and systems are FDA-compliant.
      Rochem

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      05

      Suanfarma

      Spain
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      Virtual BoothSuanfarma, at the Core of a Better Life.

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      Alpha Lipoic Acid

      About the Company : Suanfarma founded in 1993, is a B2B life science partner committed to health & innovation by developing, manufacturing, & distributing high-quality APIs for the pharmaceutical indu...

      Suanfarma founded in 1993, is a B2B life science partner committed to health & innovation by developing, manufacturing, & distributing high-quality APIs for the pharmaceutical industry innovatively & sustainably. Backed by a robust global network of 12 strategically located local offices, we cater to the needs of over 400 active customers in 70+ countries. At Suanfarma we offer our CDMO capacity for fermentation & chemical synthesis projects, offering a One Stop Shop service with a solid track record, & which allows us to achieve success in the development, scaling, manufacturing, & commercialization of an API, either innovative or generic.
      Suanfarma

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      06

      Pharm-RX Chemical

      U.S.A
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      Medlab Asia & Asia Health
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      Virtual BoothPharm-Rx is a reputed global importer and distributor of pharmaceutical active ingredients.

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      Alpha Lipoic Acid

      About the Company : Pharm-Rx has earned an outstanding reputation since its establishment in 1991, serving as a reputable importer and distributor of active ingredients to the pharmaceutical, nutritio...

      Pharm-Rx has earned an outstanding reputation since its establishment in 1991, serving as a reputable importer and distributor of active ingredients to the pharmaceutical, nutritional supplement, and food industries. The company maintains an exceptionally selective approach to its suppliers, personally visiting manufacturers overseas to ensure the highest standards. The sustained growth of Pharm-Rx can be attributed to its steadfast commitment to three core values: quality ingredients, competitive pricing, and unparalleled customer service.
      Pharm RX

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      07

      Ami Lifesciences Private Limited

      India
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      Medlab Asia & Asia Health
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      Virtual BoothAMI Lifesciences is Driven by Chemistry. Powered by People.

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      Alpha Lipoic Acid

      About the Company : Ami Lifesciences, established in 2006, is one of the fastest growing API manufacturing companies in India. Specializing in cardiovascular, anti-diabetic, CNS, and respiratory thera...

      Ami Lifesciences, established in 2006, is one of the fastest growing API manufacturing companies in India. Specializing in cardiovascular, anti-diabetic, CNS, and respiratory therapeutic areas, Ami offers a wide range of APIs, intermediates, key starting materials, as well as contract bulk manufacturing services. Ami's manufacturing units in Gujarat and Karnataka feature dedicated clean rooms for APIs and adhere to international standards like EU-GMP, WHO-GMP, PMDA, and COFEPRIS. Ami serves as a reliable partner for contract development and manufacturing, offering generic APIs to global pharma companies across more than 60 countries.
      AMI Lifesciences

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      08

      Dalian Richon Chem

      China
      Medlab Asia & Asia Health
      Not Confirmed
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      Dalian Richon Chem

      China
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      Medlab Asia & Asia Health
      Not Confirmed
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      Thioctic Acid

      About the Company : Dalian Richon Chem. Co., Ltd is a high-tech enterprise professionally involved in research and development, manufacturing process and sales service of pharmaceutical intermediates ...

      Dalian Richon Chem. Co., Ltd is a high-tech enterprise professionally involved in research and development, manufacturing process and sales service of pharmaceutical intermediates and APIs. It has passed ISO9001:2000 international quality management system certificate. Its business scope includes development and manufacturing of APIs and pharmaceutical intermediates, contract development and manufacturing for domestic and international pharmaceutical companies, technical consultation, service and transfer.
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      09

      Olon S.p.A

      Italy
      Medlab Asia & Asia Health
      Not Confirmed
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      Olon S.p.A

      Italy
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      Medlab Asia & Asia Health
      Not Confirmed
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      Alpha Lipoic Acid

      About the Company : We produce Active Pharmaceutical Ingredients (APIs) providing integrated full-service capabilities. Olon’s ability to develop and manufacture Active Pharmaceutical Ingredients (...

      We produce Active Pharmaceutical Ingredients (APIs) providing integrated full-service capabilities. Olon’s ability to develop and manufacture Active Pharmaceutical Ingredients (APIs) in our network of facilities allows clients full access to integrated services resulting in faster production and delivery timelines, with one of the most extensive track records. We rely on synthetic and biological processes both for generic and contract development and the manufacturing market, in a full cGMPs environment, following ICH Q7 compliance.
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      10

      Sinopharm

      China
      Medlab Asia & Asia Health
      Not Confirmed
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      Sinopharm

      China
      arrow
      Medlab Asia & Asia Health
      Not Confirmed
      • fda
      • EDQM
      • WHO-GMP
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      Thioctic Acid

      About the Company : China National Pharmaceutical Group Co., Ltd. (Sinopharm) is a large healthcare group directly under the State-owned Assets Supervision and Administration Commission (SASAC) of the...

      China National Pharmaceutical Group Co., Ltd. (Sinopharm) is a large healthcare group directly under the State-owned Assets Supervision and Administration Commission (SASAC) of the State Council, with 128,000 employees and a full chain in the industry covering R&D, manufacturing, logistics and distribution, retail chains, healthcare, engineering services, exhibitions and conferences, international business and financial services. Sinopharm owns over 1,100 subsidiaries and 6 listed companies which are Sinopharm Group Co., Ltd. (Sinopharm Holding), China National Medicines Corporation Ltd., China National Accord Medicines Corporation Ltd.,
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      API Reference Price

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      [{"dataSource":"API Import","activeIngredients":"","year":"2021","qtr":"Q4","strtotime":1634063400,"product":"(R)-ALPHA-LIPOIC ACID","address":"PLOT NO. 40 AND 41, 3RD FLOOR,,VEN TUREAST PLAZA, ROAD NO.2,","city":"FINANCIAL DIST NANAKRAMGUDA,TELANGA","supplier":"HUNAN HUATENG PHARMACEUTICAL CO LTD","supplierCountry":"HONG KONG","foreign_port":"NA","customer":"LAXAI LIFE SCIENCES","customerCountry":"INDIA","quantity":"1.00","actualQuantity":"1","unit":"KGS","unitRateFc":"710","totalValueFC":"869","currency":"USD","unitRateINR":"65101.1","date":"13-Oct-2021","totalValueINR":"65101.05","totalValueInUsd":"869","indian_port":"HYDERABAD AIR","hs_no":"29339990","bill_no":"5826719","productDescription":"API","marketType":"LESS REGULATED MARKET","country":"HONG KONG","selfForZScoreResived":"Pharma Grade","supplierPort":"NA","supplierAddress":"","customerAddress":"PLOT NO. 40 AND 41, 3RD FLOOR,,VEN TUREAST PLAZA, ROAD NO.2,"},{"dataSource":"API Import","activeIngredients":"","year":"2023","qtr":"Q1","strtotime":1678386600,"product":"(R)-ALPHA-LIPOIC ACID","address":"PLOT NO. 40 AND 41, 3RD FLOOR,,VEN TUREAST PLAZA, ROAD NO.2,","city":"FINANCIAL DIST NANAKRAMGUDA,TELANGA","supplier":"HUNAN HUATENG PHARMACEUTICAL CO LTD","supplierCountry":"CHINA","foreign_port":"NA","customer":"LAXAI LIFE SCIENCES","customerCountry":"INDIA","quantity":"5.80","actualQuantity":"5.8","unit":"KGS","unitRateFc":"440","totalValueFC":"2590.8","currency":"USD","unitRateINR":"36740","date":"10-Mar-2023","totalValueINR":"213092","totalValueInUsd":"2590.8","indian_port":"HYDERABAD AIR","hs_no":"29339990","bill_no":"4993610","productDescription":"API","marketType":"REGULATED MARKET","country":"CHINA","selfForZScoreResived":"Pharma Grade","supplierPort":"NA","supplierAddress":"","customerAddress":"PLOT NO. 40 AND 41, 3RD FLOOR,,VEN TUREAST PLAZA, ROAD NO.2,"},{"dataSource":"API Import","activeIngredients":"","year":"2024","qtr":"Q3","strtotime":1720377000,"product":"ALPHA-LIPOIC ACID (NOT FOR MEDICINAL USE)","address":"NO.41,RAGHUNAYAKULU STREET,","city":"CHENNAI","supplier":"KAIXIN HK TECHNOLOGY ","supplierCountry":"CHINA","foreign_port":"SHANGHAI","customer":"K.P.MANISH GLOBAL INGREDIENTS PRIVATE LIMITED","customerCountry":"INDIA","quantity":"1000.00","actualQuantity":"1000","unit":"KGS","unitRateFc":"36.2","totalValueFC":"36572","currency":"USD","unitRateINR":"3057.1","date":"08-Jul-2024","totalValueINR":"3057090","totalValueInUsd":"36572","indian_port":"JNPT","hs_no":"29362990","bill_no":"4387687","productDescription":"API","marketType":"REGULATED MARKET","country":"CHINA","selfForZScoreResived":"Non Pharma","supplierPort":"SHANGHAI","supplierAddress":"RM 2, 3F RUBY COMMERCIAL BUILDING 480 NATHAN ROAD KL, HONGKONG, CHINASDNF CHINA","customerAddress":"NO.41,RAGHUNAYAKULU STREET,"},{"dataSource":"API Import","activeIngredients":"","year":"2024","qtr":"Q3","strtotime":1727116200,"product":"ALPHA-LIPOIC ACID (NOT FOR MEDICINAL USE)","address":"NO.41,RAGHUNAYAKULU STREET,","city":"CHENNAI","supplier":"KAIXIN HK TECHNOLOGY ","supplierCountry":"CHINA","foreign_port":"SHANGHAI","customer":"K.P.MANISH GLOBAL INGREDIENTS PRIVATE LIMITED","customerCountry":"INDIA","quantity":"1250.00","actualQuantity":"1250","unit":"KGS","unitRateFc":"35.6","totalValueFC":"44924.2","currency":"USD","unitRateINR":"3011.8","date":"24-Sep-2024","totalValueINR":"3764700","totalValueInUsd":"44924.2","indian_port":"JNPT","hs_no":"29362990","bill_no":"5769398","productDescription":"API","marketType":"REGULATED MARKET","country":"CHINA","selfForZScoreResived":"Non Pharma","supplierPort":"SHANGHAI","supplierAddress":"RM 2, 3F RUBY COMMERCIAL BUILDING 4 80 NATHAN ROAD KL, HONGKONG, CHINA SDNF CHINA","customerAddress":"NO.41,RAGHUNAYAKULU STREET,"}]
      13-Oct-2021
      24-Sep-2024
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      Fillers, Diluents & Binders

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      01

      DKSH

      Switzerland
      arrow
      Cosmoprof India
      Not Confirmed
      • fda
      • EDQM
      • WHO-GMP

      Virtual BoothDKSH is your trusted partner for companies looking to grow their business in Asia & beyond.

      Brand Name : GELATIN BOVINE 140B 6M

      Application : Fillers, Diluents & Binders, Thickeners and Stabilizers

      Excipient Details : Gelatin bovine 140B 6M is used as a stabilizer in parenteral drug products and as a binder and filler in capsules, tablets, granules, and pellets.

      Pharmacopoeia Ref : CEP, GMP, EP, USP/NF

      Technical Specs : N/A

      Ingredient(s) : Gelatin Excipient

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      GELATIN BOVINE 140B 6M

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      Gangwal Healthcare

      India
      arrow
      Cosmoprof India
      Not Confirmed
      • fda
      • EDQM
      • WHO-GMP

      Virtual BoothGangwal Healthcare is powered by innovation, driving health, wellness & healing.

      Brand Name : ProBlend®

      Application : Co-Processed Excipients, Direct Compression, Disintegrants & Superdisintegrants, Fillers, Diluents & Binders, Lubricants & Glidants

      Excipient Details : ProBlend (Microcrystalline Cellulose) is used as a filler, binder, glidant, DC & co-processed excipient in tablets, capsules, and MUPS formulations.

      Pharmacopoeia Ref : USP-NF

      Technical Specs : NA

      Ingredient(s) : Microcrystalline Cellulose

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      Gangwal Healthcare ProBlend®

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      03

      DKSH

      Switzerland
      arrow
      Cosmoprof India
      Not Confirmed
      • fda
      • EDQM
      • WHO-GMP

      Virtual BoothDKSH is your trusted partner for companies looking to grow their business in Asia & beyond.

      Brand Name : GELITA

      Application : Fillers, Diluents & Binders, Thickeners and Stabilizers

      Excipient Details : Gelita RXL R² 115B BB TB Ph is used as a stabilizer in parenteral formulations and as a filler and binder in tablets, capsules, granules, and pellets.

      Pharmacopoeia Ref : CEP, GMP, EP, USP/NF

      Technical Specs : N/A

      Ingredient(s) : Gelatin Excipient

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      GELITA

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      04

      DKSH

      Switzerland
      arrow
      Cosmoprof India
      Not Confirmed
      • fda
      • EDQM
      • WHO-GMP

      Virtual BoothDKSH is your trusted partner for companies looking to grow their business in Asia & beyond.

      Brand Name : PIG SKIN GELATIN 100B 20M

      Application : Fillers, Diluents & Binders, Thickeners and Stabilizers

      Excipient Details : Pig skin gelatin 100B 20M is used as a filler and binder in capsules, tablets, pellets, and granules and as a stabilizer in parenteral formulations.

      Pharmacopoeia Ref : CEP, GMP, EP, USP/NF

      Technical Specs : N/A

      Ingredient(s) : Gelatin Excipient

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      PIG SKIN GELATIN 100B 20M

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      05

      Gangwal Healthcare

      India
      arrow
      Cosmoprof India
      Not Confirmed
      • fda
      • EDQM
      • WHO-GMP

      Virtual BoothGangwal Healthcare is powered by innovation, driving health, wellness & healing.

      Brand Name : DiCOM-DC® PL009 P60

      Application : Co-Processed Excipients, Direct Compression, Fillers, Diluents & Binders

      Excipient Details : DiCOM-DC PL009 P60 is used as a filler, binder, directly compressible, and co-processed excipient in tablets and capsules.

      Pharmacopoeia Ref : IH

      Technical Specs : NA

      Ingredient(s) : Maize Starch

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      06

      DKSH

      Switzerland
      arrow
      Cosmoprof India
      Not Confirmed
      • fda
      • EDQM
      • WHO-GMP

      Virtual BoothDKSH is your trusted partner for companies looking to grow their business in Asia & beyond.

      Brand Name : PIG SKIN GELATIN 140B 20M

      Application : Fillers, Diluents & Binders, Thickeners and Stabilizers

      Excipient Details : Pig skin gelatin 140B 20M is used as a binder and filler in pellets, granules, capsules, and tablets and as a stabilizer in parenteral products.

      Pharmacopoeia Ref : CEP, GMP, EP, USP/NF

      Technical Specs : N/A

      Ingredient(s) : Gelatin Excipient

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      PIG SKIN GELATIN 140B 20M

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      07

      Gangwal Healthcare

      India
      arrow
      Cosmoprof India
      Not Confirmed
      • fda
      • EDQM
      • WHO-GMP

      Virtual BoothGangwal Healthcare is powered by innovation, driving health, wellness & healing.

      Brand Name : DiCOM-DC® SP204

      Application : Co-Processed Excipients, Direct Compression, Fillers, Diluents & Binders, Thickeners and Stabilizers

      Excipient Details : DiCOM-DC SP204 is used as a stabilizer, filler, binder, directly compressible, and co-processed excipient in tablets and capsules.

      Pharmacopoeia Ref : In-house

      Technical Specs : NA

      Ingredient(s) : Corn Starch, Pregelatinized

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      08

      Gangwal Healthcare

      India
      arrow
      Cosmoprof India
      Not Confirmed
      • fda
      • EDQM
      • WHO-GMP

      Virtual BoothGangwal Healthcare is powered by innovation, driving health, wellness & healing.

      Brand Name : Microlose™ M60 P60

      Application : Co-Processed Excipients, Direct Compression, Fillers, Diluents & Binders

      Excipient Details : Microlose M60 P60 is used as a filler, binder, directly compressible, and co-processed excipient in tablets and capsules.

      Pharmacopoeia Ref : In-house

      Technical Specs : Lactose Monohydrate – 40%, Microcrystalline cellulose – 60%

      Ingredient(s) : Lactose Monohydrate

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      09

      Microlex e.U

      Austria
      Cosmoprof India
      Not Confirmed
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      Sigachi Industries

      India
      Cosmoprof India
      Not Confirmed
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