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    Also known as: 88637-37-0, 2-(benzhydryloxy)-n,n-dimethylethanamine 2-hydroxypropane-1,2,3-tricarboxylate, Diphenhydramine citrate [usp], Diphenhydramine (citrate), 2-benzhydryloxy-n,n-dimethylethanamine;2-hydroxypropane-1,2,3-tricarboxylic acid, 4od433s209
    Molecular Formula
    C23H29NO8
    Molecular Weight
    447.5  g/mol
    InChI Key
    SPCKHVPPRJWQRZ-UHFFFAOYSA-N
    FDA UNII
    4OD433S209
    Diphenhydramine Citrate
    A histamine H1 antagonist used as an antiemetic, antitussive, for dermatoses and pruritus, for hypersensitivity reactions, as a hypnotic, an antiparkinson, and as an ingredient in common cold preparations. It has some undesired antimuscarinic and sedative effects.
    1 2D Structure

    Diphenhydramine Citrate

    2 Identification
    2.1 Computed Descriptors
    2.1.1 IUPAC Name
    2-benzhydryloxy-N,N-dimethylethanamine;2-hydroxypropane-1,2,3-tricarboxylic acid
    2.1.2 InChI
    InChI=1S/C17H21NO.C6H8O7/c1-18(2)13-14-19-17(15-9-5-3-6-10-15)16-11-7-4-8-12-16;7-3(8)1-6(13,5(11)12)2-4(9)10/h3-12,17H,13-14H2,1-2H3;13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
    2.1.3 InChI Key
    SPCKHVPPRJWQRZ-UHFFFAOYSA-N
    2.1.4 Canonical SMILES
    CN(C)CCOC(C1=CC=CC=C1)C2=CC=CC=C2.C(C(=O)O)C(CC(=O)O)(C(=O)O)O
    2.2 Other Identifiers
    2.2.1 UNII
    4OD433S209
    2.3 Synonyms
    2.3.1 MeSH Synonyms

    1. 2-diphenylmethoxy-n,n-dimethylethylamine

    2. Allerdryl

    3. Benadryl

    4. Benhydramin

    5. Benylin

    6. Benzhydramine

    7. Citrate, Diphenhydramine

    8. Dimedrol

    9. Diphenhydramine

    10. Diphenhydramine Citrate (1:1)

    11. Diphenhydramine Hydrochloride

    12. Diphenylhydramin

    13. Diphenylhydramine

    14. Dormin

    15. Hydrochloride, Diphenhydramine

    2.3.2 Depositor-Supplied Synonyms

    1. 88637-37-0

    2. 2-(benzhydryloxy)-n,n-dimethylethanamine 2-hydroxypropane-1,2,3-tricarboxylate

    3. Diphenhydramine Citrate [usp]

    4. Diphenhydramine (citrate)

    5. 2-benzhydryloxy-n,n-dimethylethanamine;2-hydroxypropane-1,2,3-tricarboxylic Acid

    6. 4od433s209

    7. 2-(diphenylmethoxy)-n,n-dimethylethylamine Citrate (1:1)

    8. Diphenhydramine Citrate (usp)

    9. Ethanamine, 2-(diphenylmethoxy)-n,n-dimethyl-, 2-hydroxy-1,2,3-propanetricarboxylate (1:1)

    10. Unii-4od433s209

    11. Einecs 289-432-0

    12. Schembl322306

    13. Chembl1201089

    14. Dtxsid80237211

    15. Bcp12478

    16. 2-(benzhydryloxy)-n,n-dimethylethanamine2-hydroxypropane-1,2,3-tricarboxylate

    17. Akos016005048

    18. Diphenhydramine Citrate [mart.]

    19. Diphenhydramine Citrate [vandf]

    20. 2-benzhydryloxy-n,n-dimethylethanamine,2-hydroxypropane-1,2,3-tricarboxylic Acid

    21. Diphenhydramine Citrate [usp-rs]

    22. Diphenhydramine Citrate [who-dd]

    23. Diphenhydramine Citrate [orange Book]

    24. D03854

    25. Diphenhydramine Citrate [usp Monograph]

    26. 637d370

    27. Q5402419

    28. (2-(diphenylmethoxy)ethyl)dimethylammonium Dihydrogen 2-hydroxypropane-1,2,3-tricarboxylate

    2.4 Create Date
    2005-08-09
    3 Chemical and Physical Properties
    Molecular Weight 447.5 g/mol
    Molecular Formula C23H29NO8
    Hydrogen Bond Donor Count4
    Hydrogen Bond Acceptor Count9
    Rotatable Bond Count11
    Exact Mass447.18931688 g/mol
    Monoisotopic Mass447.18931688 g/mol
    Topological Polar Surface Area145 Ų
    Heavy Atom Count32
    Formal Charge0
    Complexity439
    Isotope Atom Count0
    Defined Atom Stereocenter Count0
    Undefined Atom Stereocenter Count0
    Defined Bond Stereocenter Count0
    Undefined Bond Stereocenter Count0
    Covalently Bonded Unit Count2
    4 Pharmacology and Biochemistry
    4.1 MeSH Pharmacological Classification

    Histamine H1 Antagonists

    Drugs that selectively bind to but do not activate histamine H1 receptors, thereby blocking the actions of endogenous histamine. Included here are the classical antihistaminics that antagonize or prevent the action of histamine mainly in immediate hypersensitivity. They act in the bronchi, capillaries, and some other smooth muscles, and are used to prevent or allay motion sickness, seasonal rhinitis, and allergic dermatitis and to induce somnolence. The effects of blocking central nervous system H1 receptors are not as well understood. (See all compounds classified as Histamine H1 Antagonists.)

    Anesthetics, Local

    Drugs that block nerve conduction when applied locally to nerve tissue in appropriate concentrations. They act on any part of the nervous system and on every type of nerve fiber. In contact with a nerve trunk, these anesthetics can cause both sensory and motor paralysis in the innervated area. Their action is completely reversible. (From Gilman AG, et. al., Goodman and Gilman's The Pharmacological Basis of Therapeutics, 8th ed) Nearly all local anesthetics act by reducing the tendency of voltage-dependent sodium channels to activate. (See all compounds classified as Anesthetics, Local.)

    Sleep Aids, Pharmaceutical

    Drugs used to induce SLEEP, prevent SLEEPLESSNESS, or treat SLEEP INITIATION AND MAINTENANCE DISORDERS. (See all compounds classified as Sleep Aids, Pharmaceutical.)

    Anti-Allergic Agents

    Agents that are used to treat allergic reactions. Most of these drugs act by preventing the release of inflammatory mediators or inhibiting the actions of released mediators on their target cells. (From AMA Drug Evaluations Annual, 1994, p475) (See all compounds classified as Anti-Allergic Agents.)

    Antiemetics

    Drugs used to prevent NAUSEA or VOMITING. (See all compounds classified as Antiemetics.)

    Hypnotics and Sedatives

    Drugs used to induce drowsiness or sleep or to reduce psychological excitement or anxiety. (See all compounds classified as Hypnotics and Sedatives.)

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    Pharm-RX Chemical

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    Diphenhydramine Citrate

    About the Company : Pharm-Rx has earned an outstanding reputation since its establishment in 1991, serving as a reputable importer and distributor of active ingredients to the pharmaceutical, nutritio...

    Pharm-Rx has earned an outstanding reputation since its establishment in 1991, serving as a reputable importer and distributor of active ingredients to the pharmaceutical, nutritional supplement, and food industries. The company maintains an exceptionally selective approach to its suppliers, personally visiting manufacturers overseas to ensure the highest standards. The sustained growth of Pharm-Rx can be attributed to its steadfast commitment to three core values: quality ingredients, competitive pricing, and unparalleled customer service.
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    Albemarle Corporation

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    Albemarle Corporation

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    Diphenhydramine Citrate

    About the Company : Albemarle Corporation (NYSE: ALB), headquartered in Charlotte, NC, is a global specialty chemicals company with leading positions in lithium, bromine and refining catalysts. We pow...

    Albemarle Corporation (NYSE: ALB), headquartered in Charlotte, NC, is a global specialty chemicals company with leading positions in lithium, bromine and refining catalysts. We power the potential of companies in many of the world’s largest and most critical industries, from energy and communications to transportation and electronics. Working side-by-side with our customers, we develop value-added, customized solutions that make them more competitive. Our solutions combine the finest technology and ingredients with the knowledge and know-how of our highly experienced and talented team of operators, scientists and engineers.
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    Recordati

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    Diphenhydramine Citrate

    About the Company : Recordati, established in 1926, is an international pharmaceutical group, listed on the Italian Stock Exchange (Reuters RECI.MI, Bloomberg REC IM, ISIN IT 0003828271), with a total...

    Recordati, established in 1926, is an international pharmaceutical group, listed on the Italian Stock Exchange (Reuters RECI.MI, Bloomberg REC IM, ISIN IT 0003828271), with a total staff of around 4,000, dedicated to the research, development, manufacturing and marketing of pharmaceuticals. Headquartered in Milan, Italy, Recordati has operations in the main European countries, in Russia, in other Central and Eastern European countries, in Turkey, in North Africa and in the United States of America.
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    S.S.Pharmachem

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    S.S.Pharmachem

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    Diphenhydramine Citrate

    About the Company : S.S. PHARMACHEM is a professionally managed Bulk Drug & Chemical manufacturing unit headed by MR. SAGAR S. SANGEKAR & MR. SANJAY S. SANGEKAR. Established in 1987 & committed to dev...

    S.S. PHARMACHEM is a professionally managed Bulk Drug & Chemical manufacturing unit headed by MR. SAGAR S. SANGEKAR & MR. SANJAY S. SANGEKAR. Established in 1987 & committed to development of import substitutes. S.S. PHARMACHEM has evolved into highly organized concern comprising of a sophisticated manufacturing complex at Tarapur (Maharashtra). Our Specialized product range has been well accepted by Indian as well as multinational companies. We also export our products to various countries. Our List of Customer include many customers all over the world in U.S.A, EUROPE, CANADA, SINGAPORE, TAIWAN, THAILAND, EGYPT, JORDAN, OMAN, NEPAL, PAKISTAN etc..... Also some of our local customers are multinationals like JOHNSON & JOHNSON, CIPLA, IPCA, INDOCO REMIDIES, AJANTA PHARMA, SHASUN CHEMICALS and many more. Our manufacturing facility has been Audited by companies like JOHNSON & JOHNSON, ABBOTT, IPCA, CIPLA, DR.REDDYS, SHASUN CHEMICALS and also some of our foreign buyers such as SANDOZ CANADA. One of our main products is Diphenhydramine Hcl, Diethyl Carbamazine Citrate, Ambroxol Hcl, Mephenesin, Dimenhydrinate, Maleic Acid. Please also see our attached product List for our entire product range and monthly capacity.
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    API Reference Price

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    [{"dataSource":"API Export","activeIngredients":"","year":"2022","qtr":"Q4","strtotime":1669141800,"product":"DIPHENHYDRAMINE CITRATE U.S.P.","address":"FLAT NO 502 A WING HUBTOWN SUNMIST ,CTS 426 OFF N S PHADAKE ROAD","city":"SAIWADI ANDHER EAST MUMBAI,MAHARASH","supplier":"S.S.PHARMACHEM","supplierCountry":"INDIA","foreign_port":"SANTIAGO DE CHILE -","customer":"TO,","customerCountry":"CHILE","quantity":"5.00","actualQuantity":"5","unit":"KGS","unitRateFc":"155","totalValueFC":"722.9","currency":"USD","unitRateINR":11800,"date":"23-Nov-2022","totalValueINR":"59000","totalValueInUsd":"722.9","indian_port":"BOMBAY AIR","hs_no":"29420090","bill_no":"5659817","productDescription":"API","marketType":"REGULATED MARKET","country":"CHILE","selfForZScoreResived":"Pharma Grade","supplierPort":"BOMBAY AIR","supplierAddress":"FLAT NO 502 A WING HUBTOWN SUNMIST ,CTS 426 OFF N S PHADAKE ROAD, SAIWADI ANDHER EAST MUMBAI,MAHARASH","customerAddress":""},{"dataSource":"API Export","activeIngredients":"","year":"2022","qtr":"Q4","strtotime":1669833000,"product":"DIPHENHYDRAMINE CITRATE USP","address":"BSEL TECH PARK B WING10TH FLR SECTOR 30 A OPP VASHI RAILWAY CONTA","city":"STATION VASHI NAVI MUMBAI MAHARASHT","supplier":"WANBURY LIMITED","supplierCountry":"INDIA","foreign_port":"TEL AVIV YAFO","customer":"TO THE ORDER OF","customerCountry":"ISRAEL","quantity":"25.00","actualQuantity":"25","unit":"KGS","unitRateFc":"26","totalValueFC":"643.2","currency":"USD","unitRateINR":2120,"date":"01-Dec-2022","totalValueINR":"53000","totalValueInUsd":"643.2","indian_port":"HYDERABAD AIR","hs_no":"29214490","bill_no":"5862404","productDescription":"API","marketType":"LESS REGULATED MARKET","country":"ISRAEL","selfForZScoreResived":"Pharma Grade","supplierPort":"HYDERABAD AIR","supplierAddress":"BSEL TECH PARK B WING10TH FLR SECTOR 30 A OPP VASHI RAILWAY CONTA, STATION VASHI NAVI MUMBAI MAHARASHT","customerAddress":""},{"dataSource":"API Export","activeIngredients":"","year":"2023","qtr":"Q2","strtotime":1681842600,"product":"BULK DRUG-DIPHENHYDRAMINE CITRATE USP 43","address":"A-201\/202, NAVBHARAT EST.,,ZAKARIA BUNDER RD.,SEWRI WEST,","city":"MUMBAI,MAHARASHTRA","supplier":"GEMINI EXPORTS","supplierCountry":"INDIA","foreign_port":"CAIRO","customer":"THE","customerCountry":"EGYPT","quantity":"50.00","actualQuantity":"50","unit":"KGS","unitRateFc":"35","totalValueFC":"1488.6","currency":"USD","unitRateINR":2440,"date":"19-Apr-2023","totalValueINR":"122000","totalValueInUsd":"1488.6","indian_port":"BOMBAY AIR","hs_no":"29420090","bill_no":"9393935","productDescription":"API","marketType":"LESS REGULATED MARKET","country":"EGYPT","selfForZScoreResived":"Pharma Grade","supplierPort":"BOMBAY AIR","supplierAddress":"A-201\/202, NAVBHARAT EST.,,ZAKARIA BUNDER RD.,SEWRI WEST,, MUMBAI,MAHARASHTRA","customerAddress":""},{"dataSource":"API Export","activeIngredients":"","year":"2023","qtr":"Q3","strtotime":1693506600,"product":"DIPHENHYDRAMINE CITRATE (INV.NO:92005509DT:23.08.2023)","address":"BSEL TECH PARK,B-WING,10TH FLR,SECTOR -30 A,OPP.VA","city":"STATION,VASHI,NAVI MUMBAI ,MAHARASH","supplier":"WANBURY LIMITED","supplierCountry":"INDIA","foreign_port":"SAN SALVADOR","customer":"TO THE ORDER OF","customerCountry":"EL SALVADOR","quantity":"25.00","actualQuantity":"25","unit":"KGS","unitRateFc":"155","totalValueFC":"3578","currency":"USD","unitRateINR":11880,"date":"01-Sep-2023","totalValueINR":"297000","totalValueInUsd":"3578","indian_port":"Hyderabad Air","hs_no":"29214490","bill_no":"3645532","productDescription":"API","marketType":"LESS REGULATED MARKET","country":"EL SALVADOR","selfForZScoreResived":"Pharma Grade","supplierPort":"Hyderabad Air","supplierAddress":"BSEL TECH PARK,B-WING,10TH FLR,SECTOR -30 A,OPP.VA, STATION,VASHI,NAVI MUMBAI ,MAHARASH","customerAddress":""},{"dataSource":"API Import","activeIngredients":"","year":"2021","qtr":"Q4","strtotime":1635445800,"product":"DIPHENHYDRAMINE CITRATE","address":"PLOT NO.N- 39 AND PLOT NO. N- 39\/1, ADDITIONAL AMBERNATH MIDC, ANAND","city":"NAGAR,AMBERNATH(EAST) THANEH","supplier":"RECORDATI","supplierCountry":"ITALY","foreign_port":"NA","customer":"PERRIGO COMPANY PLC","customerCountry":"INDIA","quantity":"22.00","actualQuantity":"22","unit":"KGS","unitRateFc":"90","totalValueFC":"2003.5","currency":"USD","unitRateINR":"6822","date":"29-Oct-2021","totalValueINR":"150084","totalValueInUsd":"2003.5","indian_port":"BOMBAY AIR","hs_no":"29181520","bill_no":"6043299","productDescription":"API","marketType":"REGULATED MARKET","country":"ITALY","selfForZScoreResived":"Pharma Grade","supplierPort":"NA","supplierAddress":"","customerAddress":"PLOT NO.N- 39 AND PLOT NO. N- 39\/1, ADDITIONAL AMBERNATH MIDC, ANAND"}]
    29-Oct-2021
    01-Sep-2023
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