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    Chemistry

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    Also known as: 919-16-4, Trilithium citrate, Litarex, Citric acid trilithium salt, Lithium citrate anhydrous, Lithium (citrate)
    Molecular Formula
    C6H5Li3O7
    Molecular Weight
    210.0  g/mol
    InChI Key
    WJSIUCDMWSDDCE-UHFFFAOYSA-K
    FDA UNII
    3655633623
    Lithium Citrate
    Lithium Citrate is the citrate salt of lithium, a monovalent cation with antimanic activity. Although the exact mechanism is unclear, lithium might exert its mood-stabilizing effect via reduction of catecholamine concentration mediated through transneuronal membrane transport of sodium ion by sodium-potassium-stimulated adenosine triphosphatase (Na-K-ATPase). Alternatively, lithium may decrease cyclic adenosine monophosphate (cAMP) concentrations, which would desensitize hormonal-sensitive adenylyl cyclase receptors. Furthermore, lithium, in recommended dosage, blocks the activity of inositol-1-phosphatase, thereby resulting in the subsequent decrease of postsynaptic second messengers, diacylglycerol and inositol triphosphate, that contribute to chronic cell stimulation by altering electrical activity in the neuron.
    1 2D Structure

    Lithium Citrate

    2 Identification
    2.1 Computed Descriptors
    2.1.1 IUPAC Name
    trilithium;2-hydroxypropane-1,2,3-tricarboxylate
    2.1.2 InChI
    InChI=1S/C6H8O7.3Li/c7-3(8)1-6(13,5(11)12)2-4(9)10;;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;;/q;3*+1/p-3
    2.1.3 InChI Key
    WJSIUCDMWSDDCE-UHFFFAOYSA-K
    2.1.4 Canonical SMILES
    [Li+].[Li+].[Li+].C(C(=O)[O-])C(CC(=O)[O-])(C(=O)[O-])O
    2.2 Other Identifiers
    2.2.1 UNII
    3655633623
    2.3 Synonyms
    2.3.1 MeSH Synonyms

    1. Litarex

    2. Monolithium Citrate

    2.3.2 Depositor-Supplied Synonyms

    1. 919-16-4

    2. Trilithium Citrate

    3. Litarex

    4. Citric Acid Trilithium Salt

    5. Lithium Citrate Anhydrous

    6. Lithium (citrate)

    7. Citric Acid, Trilithium Salt

    8. Lithium Citrate (anhydrous)

    9. Lithium Citrate Tribasic Tetrahydrate

    10. 1,2,3-propanetricarboxylic Acid, 2-hydroxy-, Trilithium Salt

    11. Anhydrous Lithium Citrate

    12. Demalit; Litarex; Lithonate S

    13. 6680-58-6

    14. Demalit

    15. Chebi:64735

    16. Lithium 2-hydroxypropane-1,2,3-tricarboxylate

    17. Trilithium;2-hydroxypropane-1,2,3-tricarboxylate

    18. 1,2,3-propanetricarboxylic Acid, 2-hydroxy-, Lithium Salt (1:3)

    19. Einecs 213-045-8

    20. Citric Acid, Lithium Salt

    21. Trilithium 2-hydroxypropane-1,2,3-tricarboxylate

    22. Einecs 233-819-9

    23. Anh. Lithium Citrate

    24. Unii-3655633623

    25. Lithium Citrate (anh.)

    26. Citric Acid,lithium Salt

    27. Lithium Citrate [mi]

    28. Spectrum1504269

    29. Chembl1201170

    30. Dtxsid70883185

    31. Hms1923k13

    32. Hms2093g04

    33. Lithium Citrate Tribasic 4-hydrate

    34. 2-hydroxy-1,2,3-propanetricarboxylic Acid Lithium Salt (1:3)

    35. Akos015839591

    36. Akos015902460

    37. Ccg-213298

    38. Db14507

    39. Ncgc00095267-01

    40. Ncgc00095267-02

    41. 1313437-84-1

    42. Db-054961

    43. Ft-0636234

    44. Lithium2-hydroxypropane-1,2,3-tricarboxylate

    45. Lithium 3-carboxy-3,5-dihydroxy-5-oxopentanoate

    46. Q2351742

    2.4 Create Date
    2005-08-08
    3 Chemical and Physical Properties
    Molecular Weight 210.0 g/mol
    Molecular Formula C6H5Li3O7
    Hydrogen Bond Donor Count1
    Hydrogen Bond Acceptor Count7
    Rotatable Bond Count2
    Exact Mass210.0515378 g/mol
    Monoisotopic Mass210.0515378 g/mol
    Topological Polar Surface Area141 Ų
    Heavy Atom Count16
    Formal Charge0
    Complexity211
    Isotope Atom Count0
    Defined Atom Stereocenter Count0
    Undefined Atom Stereocenter Count0
    Defined Bond Stereocenter Count0
    Undefined Bond Stereocenter Count0
    Covalently Bonded Unit Count4
    4 Drug and Medication Information
    4.1 Drug Information
    1 of 2  
    Drug NameLithium citrate
    Active IngredientLithium citrate
    Dosage FormSyrup
    RouteOral
    Strengtheq 300mg carbonate/5ml
    Market StatusPrescription
    CompanyWockhardt; Roxane

    2 of 2  
    Drug NameLithium citrate
    Active IngredientLithium citrate
    Dosage FormSyrup
    RouteOral
    Strengtheq 300mg carbonate/5ml
    Market StatusPrescription
    CompanyWockhardt; Roxane

    4.2 Drug Indication

    Lithium is used as a mood stabilizer, and is used for treatment of depression and mania. It is often used in bipolar disorder treatment.

    5 Pharmacology and Biochemistry
    5.1 Pharmacology

    Although lithium has been used for over 50 years in treatment of bipolar disorder, the mechanism of action is still unknown. Lithium's therapeutic action may be due to a number of effects, ranging from inhibition of enzymes such as glycogen synthase kinase 3, inositol phosphatases, or modulation of glutamate receptors.

    5.2 Mechanism of Action

    The precise mechanism of action of Li+ as a mood-stabilizing agent is currently unknown. It is possible that Li+ produces its effects by interacting with the transport of monovalent or divalent cations in neurons. An increasing number of scientists have come to the conclusion that the excitatory neurotransmitter glutamate is the key factor in understanding how lithium works. Lithium has been shown to change the inward and outward currents of glutamate receptors (especially GluR3), without a shift in reversal potential. Lithium has been found to exert a dual effect on glutamate receptors, acting to keep the amount of glutamate active between cells at a stable, healthy level, neither too much nor too little. It is postulated that too much glutamate in the space between neurons causes mania, and too little, depression. Another mechanism by which lithium might help to regulate mood include the non-competitive inhibition of an enzyme called inositol monophosphatase. Alternately lithium's action may be enhanced through the deactivation of the GSK-3B enzyme. The regulation of GSK-3B by lithium may affect the circadian clock. GSK-3 is known for phosphorylating and thus inactivating glycogen synthase. GSK-3B has also been implicated in the control of cellular response to damaged DNA. GSK-3 normally phosphorylates beta catenin, which leads to beta catenin degratation. When GSK-3 is inhibited, beta catenin increases and transgenic mice with overexpression of beta catenin express similar behaviour to mice treated with lithium. These results suggest that increase of beta catenin may be a possible pathway for the therapeutic action of lithium.

    API SUPPLIERS

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    01

    Anmol Chemicals

    India

    USDMF, CEP/COS, JDMF, EU-WC, NDC, KDMF, VMF, Others

    Duphat
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    Anmol Chemicals

    India

    USDMF, CEP/COS, JDMF, EU-WC, NDC, KDMF, VMF, Others

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    Duphat
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    ✖

    GDUFA

    DMF Review : N/A

    Rev. Date :

    Pay. Date :

    DMF Number : 37189

    Submission : 2022-06-17

    Status : Active

    Type : IV

     CEP/COS JDMF EU-WC NDC KDMF VMF Others AUDIT
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    Solvay Chemicals International S.A

    Belgium

    USDMF, CEP/COS, JDMF, EU-WC, NDC, KDMF, VMF, Others

    Duphat
    Not Confirmed
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    Solvay Chemicals International S.A

    Belgium

    USDMF, CEP/COS, JDMF, EU-WC, NDC, KDMF, VMF, Others

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    Duphat
    Not Confirmed
    USDMF Inactive-api
    ✖

    GDUFA

    DMF Review : N/A

    Rev. Date :

    Pay. Date :

    DMF Number : 1320

    Submission : 1969-02-10

    Status : Inactive

    Type : II

     CEP/COS JDMF EU-WC NDC KDMF VMF Others AUDIT
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    API Reference Price

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    [{"dataSource":"API Export","activeIngredients":"","year":"2024","qtr":"Q3","strtotime":1723141800,"product":"ORGENIC CHEMICALS -CHAPTER 29.AS PER INVOICE NUMBER. EXP-93 FOR INDUSTRIAL USE ONLY LITHIUM CITRATE (ANHYDROU","address":"23, MEHABOOB MANSION, 2ND","city":"MUMBAI, MAHARASHTRA","supplier":"ANMOL CHEMICALS PRIVATE LIMITED","supplierCountry":"INDIA","foreign_port":"NEW YORK","customer":"TO THE ORDER OF.,.","customerCountry":"UNITED STATES","quantity":"0.30","actualQuantity":"300","unit":"GMS","unitRateFc":"12.5","totalValueFC":"3698.1","currency":"USD","unitRateINR":1033.9679666666668,"date":"09-Aug-2024","totalValueINR":"310190.39","totalValueInUsd":"3698.1","indian_port":"Bombay Air","hs_no":"29181590","bill_no":"3098787","productDescription":"API","marketType":"REGULATED MARKET","country":"UNITED STATES","selfForZScoreResived":"Pharma Grade","supplierPort":"Bombay Air","supplierAddress":"23, MEHABOOB MANSION, 2ND, MUMBAI, MAHARASHTRA","customerAddress":""},{"dataSource":"API Import","activeIngredients":"","year":"2021","qtr":"Q4","strtotime":1638210600,"product":"TRI-LITHIUM CITRATE TETRAHYDRATE EMPROVE ESSENTIAL PH EUR,BP 9 PCS X 20 KG (PHARMA GRADE)","address":"GODREJ ONE, 8TH FLR, PIROJSHANAGAR, EASTERN EXPRESS HIGHWAY VIKHROLI-E","city":"MUMBAI","supplier":"MERCK GROUP","supplierCountry":"GERMANY","foreign_port":"NA","customer":"MERCK GROUP","customerCountry":"INDIA","quantity":"180.00","actualQuantity":"180","unit":"KGS","unitRateFc":"9361.7","totalValueFC":"22652.4","currency":"INR","unitRateINR":"9372","date":"30-Nov-2021","totalValueINR":"1686956.01","totalValueInUsd":"22652.4","indian_port":"BOMBAY AIR","hs_no":"29181590","bill_no":"6469581","productDescription":"API","marketType":"REGULATED MARKET","country":"GERMANY","selfForZScoreResived":"Pharma Grade","supplierPort":"NA","supplierAddress":"","customerAddress":"GODREJ ONE, 8TH FLR, PIROJSHANAGAR, EASTERN EXPRESS HIGHWAY VIKHROLI-E"},{"dataSource":"API Import","activeIngredients":"","year":"2023","qtr":"Q4","strtotime":1698345000,"product":"TRI-LITHIUM CITRATE TETRAHYDRATE EMPROVE ESSENTIAL PH EUR,BP 9PCS X 20KG (PHARMA GRADE)","address":"50A , RING ROAD,","city":"BANGALORE, KARNATAKA","supplier":"MERCK LIFE SCIENCE KGAA","supplierCountry":"GERMANY","foreign_port":"FRANKFURT\/MAIN INT\\'L","customer":"MERCK GROUP","customerCountry":"INDIA","quantity":"180.00","actualQuantity":"180","unit":"KGS","unitRateFc":"9441.3","totalValueFC":"20486","currency":"INR","unitRateINR":"9472.4","date":"27-Oct-2023","totalValueINR":"1705037.26","totalValueInUsd":"20486","indian_port":"Bombay Air","hs_no":"29181590","bill_no":"8497450","productDescription":"API","marketType":"REGULATED MARKET","country":"GERMANY","selfForZScoreResived":"Pharma Grade","supplierPort":"FRANKFURT\/MAIN INT\\'L","supplierAddress":"Frankfurter Strasse 250, 64293 Darmstadt,(BENEFICIARY MERCKFINANCIALSSERVICES GMBH) GERMANY","customerAddress":"50A , RING ROAD,"},{"dataSource":"API Import","activeIngredients":"","year":"2024","qtr":"Q2","strtotime":1713205800,"product":"TRI-LITHIUM CITRATE TETRAHYDRATE EMPROVE ESSENTIAL PH EUR,BP 2PCS X 20KG (PHARMA GRADE)","address":"50A , RING ROAD,","city":"BANGALORE, KARNATAKA","supplier":"MERCK LIFE SCIENCE KGAA","supplierCountry":"GERMANY","foreign_port":"FRANKFURT\/MAIN INT\\'L","customer":"MERCK GROUP","customerCountry":"INDIA","quantity":"40.00","actualQuantity":"40","unit":"KGS","unitRateFc":"9857.9","totalValueFC":"4733.7","currency":"INR","unitRateINR":"9882.5","date":"16-Apr-2024","totalValueINR":"395300.63","totalValueInUsd":"4733.7","indian_port":"Bombay Air","hs_no":"29181590","bill_no":"3049835","productDescription":"API","marketType":"REGULATED MARKET","country":"GERMANY","selfForZScoreResived":"Pharma Grade","supplierPort":"FRANKFURT\/MAIN INT\\'L","supplierAddress":"Frankfurter Strasse 25064293 Darmstadt Germany (BENEFICIARY MERCKFINANCIAL SERVICES GMBH) GERMANY","customerAddress":"50A , RING ROAD,"},{"dataSource":"API Import","activeIngredients":"","year":"2024","qtr":"Q3","strtotime":1720549800,"product":"TRI-LITHIUM CITRATE TETRAHYDRATE EMPROVE ESSENTIAL PH EUR,BP 2PCS X 20KG (PHARMA GRADE)","address":"50A , RING ROAD,","city":"BANGALORE, KARNATAKA","supplier":"MERCK LIFE SCIENCE KGAA","supplierCountry":"GERMANY","foreign_port":"FRANKFURT\/MAIN INT\\'L","customer":"MERCK GROUP","customerCountry":"INDIA","quantity":"40.00","actualQuantity":"40","unit":"KGS","unitRateFc":"9857.9","totalValueFC":"4729","currency":"INR","unitRateINR":"9882.5","date":"10-Jul-2024","totalValueINR":"395300.63","totalValueInUsd":"4729","indian_port":"Bombay Air","hs_no":"29181590","bill_no":"4424609","productDescription":"API","marketType":"REGULATED MARKET","country":"GERMANY","selfForZScoreResived":"Pharma Grade","supplierPort":"FRANKFURT\/MAIN INT\\'L","supplierAddress":"Frankfurter Strasse 250, 64293 Darmstadt,(BENEFICIARY MERCKFINANCIALSSERVICES GMBH) GERMANY","customerAddress":"50A , RING ROAD,"}]
    30-Nov-2021
    09-Aug-2024
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    ABOUT THIS PAGE

    Lithium Citrate Manufacturers

    A Lithium Citrate manufacturer is defined as any person or entity involved in the manufacture, preparation, processing, compounding or propagation of Lithium Citrate, including repackagers and relabelers. The FDA regulates Lithium Citrate manufacturers to ensure that their products comply with relevant laws and regulations and are safe and effective to use. Lithium Citrate API Manufacturers are required to adhere to Good Manufacturing Practices (GMP) to ensure that their products are consistently manufactured to meet established quality criteria.

    Lithium Citrate Suppliers

    A Lithium Citrate supplier is an individual or a company that provides Lithium Citrate active pharmaceutical ingredient (API) or Lithium Citrate finished formulations upon request. The Lithium Citrate suppliers may include Lithium Citrate API manufacturers, exporters, distributors and traders.

    click here to find a list of Lithium Citrate suppliers with USDMF, JDMF, KDMF, CEP, GMP, COA and API Price related information on PharmaCompass.

    Lithium Citrate USDMF

    A Lithium Citrate DMF (Drug Master File) is a document detailing the whole manufacturing process of Lithium Citrate active pharmaceutical ingredient (API) in detail. Different forms of Lithium Citrate DMFs exist exist since differing nations have different regulations, such as Lithium Citrate USDMF, ASMF (EDMF), JDMF, CDMF, etc.

    A Lithium Citrate DMF submitted to regulatory agencies in the US is known as a USDMF. Lithium Citrate USDMF includes data on Lithium Citrate's chemical properties, information on the facilities and procedures used, and details about packaging and storage. The Lithium Citrate USDMF is kept confidential to protect the manufacturer’s intellectual property.

    click here to find a list of Lithium Citrate suppliers with USDMF on PharmaCompass.

    Lithium Citrate GMP

    Lithium Citrate Active pharmaceutical ingredient (API) is produced in GMP-certified manufacturing facility.

    GMP stands for Good Manufacturing Practices, which is a system used in the pharmaceutical industry to make sure that goods are regularly produced and monitored in accordance with quality standards. The FDA’s current Good Manufacturing Practices requirements are referred to as cGMP or current GMP which indicates that the company follows the most recent GMP specifications. The World Health Organization (WHO) has its own set of GMP guidelines, called the WHO GMP. Different countries can also set their own guidelines for GMP like China (Chinese GMP) or the EU (EU GMP).

    PharmaCompass offers a list of Lithium Citrate GMP manufacturers, exporters & distributors, which can be sorted by USDMF, JDMF, KDMF, CEP (COS), WC, API price, and more, enabling you to easily find the right Lithium Citrate GMP manufacturer or Lithium Citrate GMP API supplier for your needs.

    Lithium Citrate CoA

    A Lithium Citrate CoA (Certificate of Analysis) is a formal document that attests to Lithium Citrate's compliance with Lithium Citrate specifications and serves as a tool for batch-level quality control.

    Lithium Citrate CoA mostly includes findings from lab analyses of a specific batch. For each Lithium Citrate CoA document that a company creates, the USFDA specifies specific requirements, such as supplier information, material identification, transportation data, evidence of conformity and signature data.

    Lithium Citrate may be tested according to a variety of international standards, such as European Pharmacopoeia (Lithium Citrate EP), Lithium Citrate JP (Japanese Pharmacopeia) and the US Pharmacopoeia (Lithium Citrate USP).

    Inform the supplier about your product requirements, specifying if you need a product with particular monograph like EP (Ph. Eur.), USP, JP, BP, or any other quality. In addition, clarify whether you need hydrochloride (HCl), anhydricum, base, micronisatum or a specific level of purity. To find reputable suppliers, utilize the filters and select those certified by GMP, FDA, or any other certification as per your requirement.
    For your convenience, we have listed synonyms and CAS numbers to help you find the best supplier. The use of synonyms and CAS numbers can be helpful in identifying potential suppliers, but it is crucial to note that they might not always indicate the exact same product. It is important to confirm the product details with the supplier before making a purchase to ensure that it meets your requirements.
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