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ACTIVE PHARMA INGREDIENTS

5 API Suppliers, 3 CEP/COS, 1 JDMF, 1 EU WC, 2 Listed Suppliers, $ API Reference Price

5 API Suppliers
3 CEP/COS
1 JDMF
1 EU WC
2 Listed Suppliers
$ API Reference Price

FINISHED DOSAGE FORMULATIONS

9 FDF Dossiers, 7 Europe, 2 Listed Dossiers

9 FDF Dossiers
7 Europe
2 Listed Dossiers

DIGITAL CONTENT

1 DATA COMPILATION #PharmaFlow, 1 NEWS #PharmaBuzz

media
1 DATA COMPILATION #PharmaFlow
1 NEWS #PharmaBuzz

GLOBAL SALES INFORMATION

2 Finished Drug Prices

globalSalesInformation
2 Finished Drug Prices

MARKET PLACE

6 APIs

marketPlace
6 APIs

REF. STANDARDS & IMPURITIES

1 EDQM

otherSolutions
1 EDQM

Synopsis

ACTIVE PHARMA INGREDIENTS

API Suppliers

USDMF

CEP/COS

JDMF

EU WC

KDMF

NDC API

VMF

Listed Suppliers

API REF. PRICE (USD/KG)

$ 26

MARKET PLACE

API

FDF

0INTERMEDIATES

FINISHED DOSAGE FORMULATIONS

FDF Dossiers

FDA Orange Book

Europe

Canada

Australia

South Africa

Listed Dossiers

0 DRUGS IN DEVELOPMENT

DRUG PRODUCT COMPOSITIONS

REF. STANDARDS OR IMPURITIES

EDQM

USP

Others

PATENTS & EXCLUSIVITIES

US Patents

US Exclusivities

Health Canada Patents

DIGITAL CONTENT

Data Compilation #PharmaFlow

Stock Recap #PipelineProspector

Weekly News Recap #Phispers

News #PharmaBuzz

GLOBAL SALES INFORMATION

US Medicaid (USD)

Annual Reports (USD Million)

Finished Drug Prices

0RELATED EXCIPIENT COMPANIES

0EXCIPIENTS BY APPLICATIONS

Chemistry

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Also known as: Isopropyl phenazone, 479-92-5, Isopropylantipyrine, Isopropylphenazone, 4-isopropylantipyrine, Isopropyrine

Molecular Formula

C₁₄H₁₈N₂O

Molecular Weight

230.31 g/mol

InChI Key

PXWLVJLKJGVOKE-UHFFFAOYSA-N

FDA UNII

OED8FV75PY

1 2D Structure

Propyphenazone

2 Identification

2.1 Computed Descriptors

2.1.1 IUPAC Name

1,5-dimethyl-2-phenyl-4-propan-2-ylpyrazol-3-one

2.1.2 InChI

InChI=1S/C14H18N2O/c1-10(2)13-11(3)15(4)16(14(13)17)12-8-6-5-7-9-12/h5-10H,1-4H3

2.1.3 InChI Key

PXWLVJLKJGVOKE-UHFFFAOYSA-N

2.1.4 Canonical SMILES

CC1=C(C(=O)N(N1C)C2=CC=CC=C2)C(C)C

2.2 Other Identifiers

2.2.1 UNII

OED8FV75PY

2.3 Synonyms

2.3.1 MeSH Synonyms

1. 4-isopropyl-2,3-dimethyl-1-phenyl-3-pyrazoline-5-one

2. 4-isopropylantipyrine

3. Commotional

4. Demex

5. Hewedolor Propy

6. Isoprochin P

7. Isopropylphenazone

8. Propylphenazone

2.3.2 Depositor-Supplied Synonyms

1. Isopropyl Phenazone

2. 479-92-5

3. Isopropylantipyrine

4. Isopropylphenazone

5. 4-isopropylantipyrine

6. Isopropyrine

7. Isopropylantipyrin

8. Larodon

9. Isopropylantipyrinum

10. Propifenazona

11. Propyphenazonum

12. Propyphenazon

13. Budirol

14. Cibalgina

15. Yoshipyrin

16. 1,5-dimethyl-2-phenyl-4-propan-2-ylpyrazol-3-one

17. 1-phenyl-2,3-dimethyl-4-isopropyl-3-pyrazolin-5-one

18. 1-phenyl-2,3-dimethyl-4-isopropylpyrazol-5-one

19. 4-isopropyl-2,3-dimethyl-1-phenyl-3-pyrazolin-5-one

20. Antipyrine, 4-isopropyl-

21. Chebi:135538

22. 3h-pyrazol-3-one, 1,2-dihydro-1,5-dimethyl-4-(1-methylethyl)-2-phenyl-

23. Oed8fv75py

24. 4-isopropyl-1,5-dimethyl-2-phenyl-1,2-dihydro-pyrazol-3-one

25. 2,3-dimethyl-4-isopropyl-1-phenyl-3h-pyrazolin-5-one

26. 3-pyrazolin-5-one, 2,3-dimethyl-4-isopropyl-1-phenyl-

27. 3-pyrazolin-5-one, 4-isopropyl-2,3-dimethyl-1-phenyl-

28. 1,5-dimethyl-2-phenyl-4-(propan-2-yl)-1,2-dihydro-3h-pyrazol-3-one

29. Propyphenazone (4-isopropylantipyrine)

30. 4-isopropylantipyrine;isopropylphenazone

31. Propyphenazone (inn)

32. 4-isopropyl-1,5-dimethyl-2-phenyl-1h-pyrazol-3(2h)-one

33. Ncgc00164612-01

34. Isopropchin

35. Propifenazone

36. 4-isopropyl-1,5-dimethyl-2-phenyl-1,2-dihydro-3h-pyrazol-3-one

37. Dsstox_cid_3529

38. Dsstox_rid_77065

39. Propyphenazone [inn]

40. 4-isopropyl-2,3-dimethyl-1-phenyl-5-pyrazolone

41. Dsstox_gsid_23529

42. Propifenazone [dcit]

43. Causyth

44. Propifenazona [inn-spanish]

45. Propyphenazonum [inn-latin]

46. Cas-479-92-5

47. 4-isopropylphenazone

48. Ccris 6716

49. Propyphenazone [inn:ban:dcf]

50. Einecs 207-539-2

51. Unii-oed8fv75py

52. Brn 0204533

53. Yoshipyrin (tn)

54. 5-pyrazolone, 1-phenyl-2,3-dimethyl-4-isopropyl-

55. Propyphenazone,(s)

56. Chemdiv2_002457

57. Epitope Id:124928

58. Propyphenazone [mi]

59. Isopropylantipyrine (jp17)

60. Schembl23393

61. 5-24-01-00408 (beilstein Handbook Reference)

62. Mls004773970

63. Chembl28318

64. Propyphenazone [mart.]

65. Propyphenazone [who-dd]

66. Dtxsid6023529

67. Isopropylantipyrine [jan]

68. Pxwlvjlkjgvoke-uhfffaoysa-

69. Zinc49151

70. Hms1375p15

71. Hy-a0273

72. Tox21_112233

73. Mfcd00053368

74. Propyphenazone [ep Monograph]

75. S5309

76. Stk766727

77. 1,5-dimethyl-4-(1-methylethyl)-2-phenyl-1,2-dihydro-3h-pyrazol-3-one

78. Akos001725335

79. Tox21_112233_1

80. Ccg-266797

81. Cs-5533

82. Db13524

83. Ncgc00164612-02

84. Ac-12099

85. Bs-16890

86. Propyphenazone 1.0 Mg/ml In Acetonitrile

87. Propyphenazone 100 Microg/ml In Methanol

88. Smr001495368

89. Ft-0654525

90. I0656

91. D01380

92. D91192

93. Q425111

94. Sr-01000536454

95. 4-isopropylantipyrine, Analytical Reference Material

96. Sr-01000536454-1

97. W-106059

98. 4-isopropyl-1,5-dimethyl-2-phenyl-3-pyrazolone

99. Propyphenazone, European Pharmacopoeia (ep) Reference Standard

100. 4-isopropyl-1,5-dimethyl-2-phenyl-1,2-dihydro-3h-pyrazol-3-one #

101. Propyphenazone, Pharmaceutical Secondary Standard; Certified Reference Material

2.4 Create Date

2005-03-25

3 Chemical and Physical Properties

Molecular Formula	C₁₄H₁₈N₂O
Molecular Weight	230.31 g/mol
XLogP3	1.7
Hydrogen Bond Donor Count	0
Hydrogen Bond Acceptor Count	2
Rotatable Bond Count	2
Exact Mass	230.141913202 g/mol
Monoisotopic Mass	230.141913202 g/mol
Topological Polar Surface Area	23.6 Å²
Heavy Atom Count	17
Formal Charge	0
Complexity	340
Isotope Atom Count	0
Defined Atom Stereocenter Count	0
Undefined Atom Stereocenter Count	0
Defined Bond Stereocenter Count	0
Undefined Bond Stereocenter Count	0
Covalently Bonded Unit Count	1

4 Pharmacology and Biochemistry

4.1 MeSH Pharmacological Classification

Anti-Inflammatory Agents, Non-Steroidal

Anti-inflammatory agents that are non-steroidal in nature. In addition to anti-inflammatory actions, they have analgesic, antipyretic, and platelet-inhibitory actions. They act by blocking the synthesis of prostaglandins by inhibiting cyclooxygenase, which converts arachidonic acid to cyclic endoperoxides, precursors of prostaglandins. Inhibition of prostaglandin synthesis accounts for their analgesic, antipyretic, and platelet-inhibitory actions; other mechanisms may contribute to their anti-inflammatory effects. (See all compounds classified as Anti-Inflammatory Agents, Non-Steroidal.)

4.2 ATC Code

N - Nervous system

N02 - Analgesics

N02B - Other analgesics and antipyretics

N02BB - Pyrazolones

N02BB04 - Propyphenazone

API SUPPLIERS

01

Sanofi

France

USDMF, CEP/COS, JDMF, EU-WC, NDC, KDMF, VMF, Others

Medlab Asia & Asia Health

Not Confirmed

Sanofi is a pioneer in Diabetes Solutions, Human Vaccines, Innovative Drugs, Consumer Healthcare, and the new Genzyme.

Contact Supplier

France

Virtual Booth

Digital Content

USDMF CEP/COS

JDMF EU-WC NDC KDMF VMF Others AUDIT

Portfolio PDF

Product Web Link

02

Shandong Xinhua Pharmaceutical

China

USDMF, CEP/COS, JDMF, EU-WC, NDC, KDMF, VMF, Others

Medlab Asia & Asia Health

Not Confirmed

03

VANI PHARMA LABS LIMITED

India

USDMF, CEP/COS, JDMF, EU-WC, NDC, KDMF, VMF, Others

Medlab Asia & Asia Health

Not Confirmed

04

Kongo Chemical Co., Ltd.

Japan

USDMF, CEP/COS, JDMF, EU-WC, NDC, KDMF, VMF, Others

Medlab Asia & Asia Health

Not Confirmed

05

Stellence Pharmscience

India

USDMF, CEP/COS, JDMF, EU-WC, NDC, KDMF, VMF, Others

Medlab Asia & Asia Health

Not Confirmed

FULL SCREEN VIEW Click here to open all results in a new tab [this preview display 10 results]

CEP/COS

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JDMF

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EU WC

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Listed Suppliers

01

Shandong Xinhua Pharmaceutical

China

Medlab Asia & Asia Health

Not Confirmed

02

Stellence Pharmscience

India

Medlab Asia & Asia Health

Not Confirmed

FULL SCREEN VIEW Click here to open all results in a new tab [this preview display 10 results]

API Reference Price

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Total Value (USD)

Quantity (KGS) & Unit rate (USD/KGS) over time

API Imports and Exports

Importing Country	Total Quantity (KGS)	Average Price (USD/KGS)	Number of Transactions

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DATA COMPILATION #PharmaFlow

Niche European Molecules: is there a business opportunity worth pursuing?

New drug development is a series of complex activities invariably involving tremendous financial investment. The undertaking, to bring a new drug to market, makes it almost impossible for smaller, privately held pharmaceutical companies, to even dream of such endeavors. Is it possible for companies, lacking the resources of the pharmaceutical majors, to expand the use of existing drugs, established in some countries but not marketed in others? Our PharmaCompass analysis this week looks at products, which have monographs in the European Pharmacopoeia but have never been approved in the United States. Would it surprise you that amylmetacresol, one of the two active ingredients in Strepsils, one of the world’s largest-selling sore throat product has never been approved for use in the United States? -Reckitt Benckiser, the company that owns the Strepsils brand, markets Cepacol for sore-throat relief in the United States. While Strepsils contains, amylmetacresol and dichlorobenzyl alcohol, Cepacol has a completely different set of active ingredients i.e. benzocaine and menthol. -Interestingly, while on the topic of throat relief, pholcodine, an opioid cough suppressant, is not prescribed in the United States where it is a Schedule I drug. However, as a class B substance in the United Kingdom, it can be purchased over-the-counter (OTC) in most pharmacies. -Ergometrine, used to facilitate childbirth, while on the WHO’s essential drug list for important medications in a basic health system has also never been sold in the United States. -Hypertension and congestive heart failure drug cilazapril is sold across Canada and other European countries. Although cilazapril is supposed to have limited advantages over other drugs in the same class, exports out of India to Turkey, New Zealand and Canada indicate a robust demand in these countries. -Some molecules, discovered in France like, anti-diarrhoeal drugs nifuroxazide and racecadotril, lipid lowering ciprofibrate or anti-cancer agent buserelin are used extensively in select countries. However, for reasons unknown, they have never been approved in other parts of the world. -Lymecycline, a broad-spectrum antibiotic belonging to the tetracycline class, is used in the treatment of acne and marketed by Galderma SA, a completely owned subsidiary of Nestle. Lymecycline is 5,000 times more soluble than tetracycline base and has unique pharmacological activity amongst the tetracycline class of molecules. As the product has been on the market for over a decade, generic versions are now also available across Europe. -As antibiotics continue to get increased attention in view of the growing concern of ‘superbugs’, there are antibiotics like roxithromycin and flucloxacillin, which are sold in the UK and Australia but have never obtained approval in the United States. Are these products safe? Countries like France, United Kingdom, and Canada, where many of the above mentioned drugs are marketed, have active pharmacovigilance programs, which monitor drugs, should there be any serious adverse events. Continued use for years in well regulated pharmaceutical markets is usually proof that the products are safe. However, for the antibiotic flucloxacillin, concerns have been identified regarding a genetic link associated with liver injury. While flucloxacillin has not been approved in the United States, the FDA website does provide details on this risk. Liver toxicity concerns have limited the sales of some commonly used OTC products like nimesulide and propyphenazone (brand name: Saridon) in some countries. Yet, there are parts of the developing world, where the sales continue to increase. There are graver concerns for products like cisapride, which was launched by Janssen for increased motility of the gastrointestinal tract but was withdrawn, from the US market, due to concerns of fatalities linked to cardiac arrhythmias. The product continues to be exported from India to countries like Switzerland, Thailand, Mexico, China and Canada. Our View: Reviewing the export data out of India, on the PharmaCompass database, it is clear that in the markets, where the above mentioned products are sold, there is substantial demand. Major pharmaceutical companies have little incentive in taking old molecules global since there is little intellectual property protection to assure the profits that they are used to. However, for others there may be an opportunity worth considering. Launching a new product is always a Herculean challenge, but hopefully the successful use in existing patient populations, is a good starting point. API manufactures can also review these products since there may be better margins in these niche molecules when compared with others, which have become commodities.