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Tiotropium Bromide

Inke Tiotropium Bromide

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Valsynthese, part of the SSE Group, is a CDMO focused on highly energetic and highly hazardous chemistry.

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xyz-pharma-m-2024-10-07

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Vamsi Labs Tiotropium Bromide

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Bloomage is a one-stop source for CEP Sodium Hyaluronate and Hyaluronic Acid// FDA-inspected & GMP-certified.

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ACTIVE PHARMA INGREDIENTS

36 API Suppliers, 10 USDMF, 10 CEP/COS, 1 JDMF, 3 EU WC, 1 KDMF, 8 NDC API, 27 Listed Suppliers, $ API Reference Price

36 API Suppliers
10 USDMF
10 CEP/COS
1 JDMF
3 EU WC
1 KDMF
8 NDC API
27 Listed Suppliers
$ API Reference Price

DEVELOPMENTS

10 Drugs in Development

10 Drugs in Development

INTERMEDIATES

5 Intermediates Suppliers

5 Intermediates Suppliers

FINISHED DOSAGE FORMULATIONS

102 FDF Dossiers, 6 FDA Orange Book, 74 Europe, 5 Australia, 8 South Africa, 9 Listed Dossiers

102 FDF Dossiers
6 FDA Orange Book
74 Europe
5 Australia
8 South Africa
9 Listed Dossiers

RELATED EXCIPIENT COMPANIES

1 Faran Shimi Pharmaceutical, 3 Gangwal Healthcare, 1 Nanjing Well Pharmaceutical, 2 DFE Pharma, 14 Kerry, 2 Microlex e.U, 1 Pluviaendo, 2 Sigachi Industries

relatedExcipients
1 Faran Shimi Pharmaceutical
3 Gangwal Healthcare
1 Nanjing Well Pharmaceutical
2 DFE Pharma
14 Kerry
2 Microlex e.U
1 Pluviaendo
2 Sigachi Industries

EXCIPIENTS BY APPLICATIONS

20 Fillers, Diluents & Binders, 7 Direct Compression, 4 Granulation, 4 Co-Processed Excipients, 1 Parenteral

excipientsByApplications
20 Fillers, Diluents & Binders
7 Direct Compression
4 Granulation
4 Co-Processed Excipients
1 Parenteral

DIGITAL CONTENT

3 DATA COMPILATION #PharmaFlow, 58 NEWS #PharmaBuzz

media
3 DATA COMPILATION #PharmaFlow
58 NEWS #PharmaBuzz

GLOBAL SALES INFORMATION

1 US Medicaid Prescriptions, 39 Finished Drug Prices, 8 Annual Reports

globalSalesInformation
1 US Medicaid Prescriptions
39 Finished Drug Prices
8 Annual Reports

MARKET PLACE

10 APIs, 1 FDF Dossiers

marketPlace
10 APIs
1 FDF Dossiers

PATENTS & EXCLUSIVITIES

41 US Patents, 8 Health Canada Patents

patents
41 US Patents
8 Health Canada Patents

REF. STANDARDS & IMPURITIES

4 EDQM , 8 Others

otherSolutions
4 EDQM
8 Others

ANALYTICAL

1 BioAnalytical Methods

otherMethods
1 BioAnalytical Methods

Inke Tiotropium Bromide

Synopsis

ACTIVE PHARMA INGREDIENTS

36

API Suppliers

10

USDMF

10

CEP/COS

CEP/COS Certifications

1

JDMF

3

EU WC

1

KDMF

8

NDC API

0

VMF

27

Listed Suppliers

API REF. PRICE (USD/KG)

$

$ 188,414

MARKET PLACE

10

API

1

FDF

5INTERMEDIATES

FINISHED DOSAGE FORMULATIONS

102

FDF Dossiers

6

FDA Orange Book

FDA (Orange Book)

74

Europe

0

Canada

5

Australia

8

South Africa

9

Listed Dossiers

10DRUGS IN DEVELOPMENT

DRUG PRODUCT COMPOSITIONS

REF. STANDARDS OR IMPURITIES

4

EDQM

0

USP

0

JP

8

Others

PATENTS & EXCLUSIVITIES

41

US Patents

0

US Exclusivities

8

Health Canada Patents

DIGITAL CONTENT

3

Data Compilation #PharmaFlow

0

Stock Recap #PipelineProspector

0

Weekly News Recap #Phispers

58

News #PharmaBuzz

GLOBAL SALES INFORMATION

US Medicaid (USD)

891,532,179

Annual Reports (USD Million)

15,039

Finished Drug Prices

26 RELATED EXCIPIENT COMPANIES

36EXCIPIENTS BY APPLICATIONS

Chemistry

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Also known as: 136310-93-5, Spiriva, Ba 679 br, Tiotropium (bromide), Spiriva handihaler, Ba 679br

Molecular Formula

C₁₉H₂₂BrNO₄S₂

Molecular Weight

472.4 g/mol

InChI Key

DQHNAVOVODVIMG-RGECMCKFSA-M

FDA UNII

XX112XZP0J

Tiotropium Bromide

A scopolamine derivative and CHOLINERGIC ANTAGONIST that functions as a BRONCHODILATOR AGENT. It is used in the treatment of CHRONIC OBSTRUCTIVE PULMONARY DISEASE.

1 2D Structure

Tiotropium Bromide

2 Identification

2.1 Computed Descriptors

2.1.1 IUPAC Name

[(1R,2R,4S,5S)-9,9-dimethyl-3-oxa-9-azoniatricyclo[3.3.1.02,4]nonan-7-yl] 2-hydroxy-2,2-dithiophen-2-ylacetate;bromide

2.1.2 InChI

InChI=1S/C19H22NO4S2.BrH/c1-20(2)12-9-11(10-13(20)17-16(12)24-17)23-18(21)19(22,14-5-3-7-25-14)15-6-4-8-26-15;/h3-8,11-13,16-17,22H,9-10H2,1-2H3;1H/q+1;/p-1/t11?,12-,13+,16-,17+;

2.1.3 InChI Key

DQHNAVOVODVIMG-RGECMCKFSA-M

2.1.4 Canonical SMILES

C[N+]1(C2CC(CC1C3C2O3)OC(=O)C(C4=CC=CS4)(C5=CC=CS5)O)C.[Br-]

2.1.5 Isomeric SMILES

C[N+]1([C@@H]2CC(C[C@H]1[C@H]3[C@@H]2O3)OC(=O)C(C4=CC=CS4)(C5=CC=CS5)O)C.[Br-]

2.2 Other Identifiers

2.2.1 UNII

XX112XZP0J

2.3 Synonyms

2.3.1 MeSH Synonyms

1. 679 Br, Ba

2. 7-((hydroxybis(2-thienyl)acetyl)oxy)-9,9-dimethyl-3-oxa-9-azoniatricyclo(3.3.1.0(2,4))nonane Bromide

3. Ba 679 Br

4. Ba-679 Br

5. Ba679 Br

6. Br, Ba 679

7. Bromide, Tiotropium

8. Spiriva

9. Tiotropium

2.3.2 Depositor-Supplied Synonyms

1. 136310-93-5

2. Spiriva

3. Ba 679 Br

4. Tiotropium (bromide)

5. Spiriva Handihaler

6. Ba 679br

7. Ba-679 Br

8. Spiriva Respimat

9. (1r,2r,4s,5s,7s)-7-(2-hydroxy-2,2-di(thiophen-2-yl)acetoxy)-9,9-dimethyl-3-oxa-9-azatricyclo[3.3.1.02,4]nonan-9-ium Bromide

10. Xx112xzp0j

11. Chembl4638964

12. 7-((hydroxybis(2-thienyl)acetyl)oxy)-9,9-dimethyl-3-oxa-9-azoniatricyclo(3.3.1.0(2,4))nonane Bromide

13. Ba-679-br

14. (1r,2r,4s,5s,7r)-7-{[2-hydroxy-2,2-bis(thiophen-2-yl)acetyl]oxy}-9,9-dimethyl-3-oxa-9-azatricyclo[3.3.1.0^{2,4}]nonan-9-ium Bromide

15. (1r,2r,4s,5s,7s)-7-(2-hydroxy-2,2-di(thiophen-2-yl)acetoxy)-9,9-dimethyl-3-oxa-9-azatricyclo[3.3.1.0

16. Tiopropium

17. Tiotropium Bromide Anhydrous

18. Ba-679br

19. (1a,2b,4b,5a,7b)-7-[(hydroxydi-2-thienylacetyl)oxy]-9,9-dimethyl-3-oxa-9-azoniatricyclo[3.3.1.02,4]nonane Bromide

20. Ncgc00167971-01

21. Tiotropium Bromide [inn]

22. Unii-xx112xzp0j

23. Tiotropium Bromide [usan:inn:ban]

24. Tiotropium Bromide- Bio-x

25. Schembl8625

26. Dsstox_cid_24214

27. Dsstox_rid_80122

28. Dsstox_gsid_44214

29. Schembl440873

30. Schembl7607795

31. Tiotropium Bromide [mi]

32. Chembl3189058

33. Chembl4440620

34. Dtxsid2044214

35. Chebi:90959

36. Tiotropium Bromide [usan]

37. Hms2090h20

38. Act04740

39. Act04741

40. Amy23428

41. Bcp02925

42. Tiotropium Bromide [who-dd]

43. Tox21_112598

44. Bdbm50538220

45. Mfcd00867027

46. Akos015920264

47. Akos025400979

48. Ac-1300

49. Cs-0903

50. Ks-1402

51. Tiotropium Bromide [orange Book]

52. Tiotropium Bromide(spiriva, Ba 679br)

53. As-75172

54. Bt164474

55. Hy-17360

56. Bcp0726000293

57. Cas-136310-93-5

58. T3032

59. A846824

60. Q27162952

61. (1?,2?,4?,5?,7?)-7-[(2-hydroxy-2,2-di-2-thienylacetyl)oxy]-9,9-dimethyl-3-oxa-9-azoniatricyclo[3.3.1.02,4]nonane Bromide

62. (1alpha,2beta,4beta,5alpha,7beta)-7-[(hydroxydi-2-thienylacetyl)oxy]-9,9-dimethyl-3-oxa-9-azoniatricyclo[3.3.1.0(2,4)]nonane Bromide

63. (1r,2r,4s,5s)-7-{[2-hydroxy-2,2-bis(thiophen-2-yl)acetyl]oxy}-9,9-dimethyl-3-oxa-9-azatricyclo[3.3.1.0(2),?]nonan-9-ium Bromide

64. (1r,2r,4s,5s,7r)-7-{[2-hydroxy-2,2-bis(thiophen-2-yl)acetyl]oxy}-9,9-dimethyl-3-oxa-9-azatricyclo[3.3.1.0?,?]nonan-9-ium Bromide

65. (1r,2r,4s,5s,7s)-7-[2-hydroxy-2,2-di(2-thienyl)acetoxy]-9,9-dimethyl-3-oxa-9-azatricyclo[3.3.1.02,4]nonan-9-ium Bromide

66. [(1r,2r,4s,5s)-9,9-dimethyl-3-oxa-9-azoniatricyclo[3.3.1.02,4]nonan-7-yl] 2-hydroxy-2,2-dithiophen-2-ylacetate;bromide

67. [(1r,2r,4s,5s)-9,9-dimethyl-3-oxa-9-azoniatricyclo[3.3.1.02,4]nonan-7-yl]2-hydroxy-2,2-dithiophen-2-yl-acetate Bromide

68. 1.alpha., 2.beta., 4.beta, 5.alpha, 7.beta-7-((hydroxydi-2-thienylacetyl)oxy)-9,9-dimethyl-3-oxa-9-azoniatricyclo(3.3.1.0 Sup(2,4))nonane Bromide

69. 3-oxa-9-azoniatricyclo(3,3.1.0(2,4))nonane, 7-((hydroxydi-2-thienylacetyl)oxy)-9,9-dimethyl-, Bromide, (1alpha,2beta,4beta,5alpha,7beta)-

70. 3-oxa-9-azoniatricyclo(3.3.1.02,4)nonane, 7-((hydroxydi-2-thienacetyl)oxy)-9,9-dimethyl-, Bromide, (1.alpha.,2.beta.,4.beta.,5.alpha.,7.beta.)-

71. 3-oxa-9-azoniatricyclo[3.3.1.02,4]nonane, 7-[(2-hydroxy-2,2-di-2-thienylacetyl)oxy]-9,9-dimethyl-, Bromide (1:1), (1alpha,2beta,4beta,5alpha,7beta)-

72. 6.beta.,7.beta.-epoxy-3.beta.-hydroxy-8-methyl-1.alpha.h,5.alpha.h-tropanium Bromide, Di-2-thienylglycolate

73. Rel-(1r,2r,4s,5s,7s)-7-(2-hydroxy-2,2-di(thiophen-2-yl)acetoxy)-9,9-dimethyl-3-oxa-9-azatricyclo[3.3.1.02,4]nonan-9-ium Bromide

74. Rel-(1r,2r,4s,5s,7s)-7-(2-hydroxy-2,2-di(thiophen-2-yl)acetoxy)-9,9-dimethyl-3-oxa-9-azatricyclo[3.3.1.02,4]nonan-9-iumbromide

2.3.3 Other Synonyms

1. Tiotropiumbromide

2. Gsp 304

3. Tiotropium Cation

4. Respimat

2.4 Create Date

2005-08-08

3 Chemical and Physical Properties

Molecular Formula	C₁₉H₂₂BrNO₄S₂
Molecular Weight	472.4 g/mol
Hydrogen Bond Donor Count	1
Hydrogen Bond Acceptor Count	7
Rotatable Bond Count	5
Exact Mass	471.01736 g/mol
Monoisotopic Mass	471.01736 g/mol
Topological Polar Surface Area	116 Å²
Heavy Atom Count	27
Formal Charge	0
Complexity	564
Isotope Atom Count	0
Defined Atom Stereocenter Count	4
Undefined Atom Stereocenter Count	0
Defined Bond Stereocenter Count	0
Undefined Bond Stereocenter Count	0
Covalently Bonded Unit Count	2

4 Drug and Medication Information

4.1 Drug Information

1 of 4
Drug Name	Spiriva
PubMed Health	tiotropium
Drug Classes	Bronchodilator
Drug Label	SPIRIVA HandiHaler consists of a capsule dosage form containing a dry powder formulation of tiotropium intended for oral inhalation only with the HandiHaler device.Each light green, hard gelatin SPIRIVA capsule contains 18 mcg tiotropium (equivalent...
Active Ingredient	Tiotropium bromide
Dosage Form	Powder
Route	Inhalation
Strength	eq 0.018mg base/inh
Market Status	Prescription
Company	Boehringer Ingelheim
Patent	8022082; 6908928; RE38912; 7694676; RE39820; 7309707; 7642268; 7070800; 6777423

2 of 4
Drug Name	Spiriva respimat
PubMed Health	tiotropium
Drug Label	The active component of SPIRIVA RESPIMAT is tiotropium. The drug substance, tiotropium bromide monohydrate, is an anticholinergic with specificity for muscarinic receptors. It is chemically described as (1, 2, 4, 5, 7)-7-[(Hydroxydi-2-thien...
Active Ingredient	Tiotropium bromide
Dosage Form	Spray, metered
Route	Inhalation
Strength	eq 0.0025mg base/inh
Market Status	Prescription
Company	Boehringer Ingelheim
Patent	7284474; 7802568; 6977042; 5964416; 7988001; 6176242; 6453795; RE39820; 7246615; 6988496; 7896264; 7837235; 6726124; 6846413; 6149054; 7396341; 7104470

3 of 4
Drug Name	Spiriva
PubMed Health	tiotropium
Drug Classes	Bronchodilator
Drug Label	SPIRIVA HandiHaler consists of a capsule dosage form containing a dry powder formulation of tiotropium intended for oral inhalation only with the HandiHaler device.Each light green, hard gelatin SPIRIVA capsule contains 18 mcg tiotropium (equivalent...
Active Ingredient	Tiotropium bromide
Dosage Form	Powder
Route	Inhalation
Strength	eq 0.018mg base/inh
Market Status	Prescription
Company	Boehringer Ingelheim
Patent	8022082; 6908928; RE38912; 7694676; RE39820; 7309707; 7642268; 7070800; 6777423

4 of 4
Drug Name	Spiriva respimat
PubMed Health	tiotropium
Drug Label	The active component of SPIRIVA RESPIMAT is tiotropium. The drug substance, tiotropium bromide monohydrate, is an anticholinergic with specificity for muscarinic receptors. It is chemically described as (1, 2, 4, 5, 7)-7-[(Hydroxydi-2-thien...
Active Ingredient	Tiotropium bromide
Dosage Form	Spray, metered
Route	Inhalation
Strength	eq 0.0025mg base/inh
Market Status	Prescription
Company	Boehringer Ingelheim
Patent	7284474; 7802568; 6977042; 5964416; 7988001; 6176242; 6453795; RE39820; 7246615; 6988496; 7896264; 7837235; 6726124; 6846413; 6149054; 7396341; 7104470

5 Pharmacology and Biochemistry

5.1 MeSH Pharmacological Classification

Cholinergic Antagonists

Drugs that bind to but do not activate CHOLINERGIC RECEPTORS, thereby blocking the actions of ACETYLCHOLINE or cholinergic agonists. (See all compounds classified as Cholinergic Antagonists.)

Parasympatholytics

Agents that inhibit the actions of the parasympathetic nervous system. The major group of drugs used therapeutically for this purpose is the MUSCARINIC ANTAGONISTS. (See all compounds classified as Parasympatholytics.)

Bronchodilator Agents

Agents that cause an increase in the expansion of a bronchus or bronchial tubes. (See all compounds classified as Bronchodilator Agents.)

5.2 FDA Pharmacological Classification

5.2.1 Pharmacological Classes

Cholinergic Antagonists [MoA]; Anticholinergic [EPC]

5.3 ATC Code

R03BB04

S76 | LUXPHARMA | Pharmaceuticals Marketed in Luxembourg | Pharmaceuticals marketed in Luxembourg, as published by d'Gesondheetskeess (CNS, la caisse nationale de sante, www.cns.lu), mapped by name to structures using CompTox by R. Singh et al. (in prep.). List downloaded from https://cns.public.lu/en/legislations/textes-coordonnes/liste-med-comm.html. Dataset DOI:10.5281/zenodo.4587355

R - Respiratory system

R03 - Drugs for obstructive airway diseases

R03B - Other drugs for obstructive airway diseases, inhalants

R03BB - Anticholinergics

R03BB04 - Tiotropium bromide

API SUPPLIERS

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MAHARASHTRA","supplier":"CHEMO","supplierCountry":"ITALY","foreign_port":"MILAN - MALPENSA","customer":"GLENMARK PHARMACEUTICALS","customerCountry":"INDIA","quantity":"0.11","actualQuantity":"0.11","unit":"KGS","unitRateFc":"600000","totalValueFC":"66764.4","currency":"USD","unitRateINR":"50910000","date":"28-Aug-2024","totalValueINR":"5600100","totalValueInUsd":"66764.4","indian_port":"Bombay Air","hs_no":"29239000","bill_no":"5293647","productDescription":"API","marketType":"REGULATED MARKET","country":"ITALY","selfForZScoreResived":"Pharma Grade","supplierPort":"MILAN - MALPENSA","supplierAddress":"MANUEL POMBO ANGULO,28 3 FLOOR 28050 MADRID-SPAIN Madrid - 28050, Madrid, Spain Spain","customerAddress":"B\/2 MAHALAXMI CHAMBERS"}]

Number of Transactions

Total Quantity (KGS)

Total Value (USD)

Quantity (KGS) & Unit rate (USD/KGS) over time

API Imports and Exports

Importing Country	Total Quantity (KGS)	Average Price (USD/KGS)	Number of Transactions

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