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    Chemistry

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    Also known as: Zinc sulphate, 7733-02-0, Zinc sulfate anhydrous, Zincate, Zinc sulfate (1:1), Znso4
    Molecular Formula
    O4SZn
    Molecular Weight
    161.4  g/mol
    InChI Key
    NWONKYPBYAMBJT-UHFFFAOYSA-L
    FDA UNII
    0J6Z13X3WO
    Zinc Sulphate
    A compound given in the treatment of conditions associated with zinc deficiency such as acrodermatitis enteropathica. Externally, zinc sulfate is used as an astringent in lotions and eye drops. (Reynolds JEF(Ed): Martindale: The Extra Pharmacopoeia (electronic version). Micromedex, Inc, Englewood, CO, 1995)
    1 2D Structure

    Zinc Sulphate

    2 Identification
    2.1 Computed Descriptors
    2.1.1 IUPAC Name
    zinc;sulfate
    2.1.2 InChI
    InChI=1S/H2O4S.Zn/c1-5(2,3)4;/h(H2,1,2,3,4);/q;+2/p-2
    2.1.3 InChI Key
    NWONKYPBYAMBJT-UHFFFAOYSA-L
    2.1.4 Canonical SMILES
    [O-]S(=O)(=O)[O-].[Zn+2]
    2.2 Other Identifiers
    2.2.1 UNII
    0J6Z13X3WO
    2.3 Synonyms
    2.3.1 MeSH Synonyms

    1. Sulfate, Zinc

    2. Zinc Sulfate, Heptahydrate

    3. Zincteral

    2.3.2 Depositor-Supplied Synonyms

    1. Zinc Sulphate

    2. 7733-02-0

    3. Zinc Sulfate Anhydrous

    4. Zincate

    5. Zinc Sulfate (1:1)

    6. Znso4

    7. Sulfuric Acid, Zinc Salt (1:1)

    8. Sulfate De Zinc

    9. Zinc(ii) Sulfate

    10. Zinc Sulphate Anhydrous

    11. Zinc Sulfate, Anhydrous

    12. Zinc Sulphate, Anhydrous

    13. Zinc Sulfate (anhydrous)

    14. Zinc Sulfate Hydrate

    15. 0j6z13x3wo

    16. Chebi:35176

    17. Nsc-32677

    18. Nsc-135806

    19. Complexonat

    20. Medizinc

    21. Optised

    22. Orazinc

    23. Solvezinc

    24. Zinklet

    25. Neozin

    26. Visine-ac

    27. Zinci Sulfas

    28. Prefrin-z

    29. Zincum Sulfuricum

    30. Zink-gro

    31. Zinc Sulfate Solution

    32. Zinc Vitriol (van)

    33. Caswell No. 927

    34. White Vitriol (van)

    35. Zincsulphate

    36. Salvazinc

    37. Zinc;sulfate

    38. Nu-z

    39. Sulfuric Acid, Zinc Salt

    40. Zinc-200

    41. Sulfate De Zinc [french]

    42. Ccris 3664

    43. Sulfuric Acid Zinc Salt (van)

    44. Hsdb 1063

    45. Einecs 231-793-3

    46. Nsc 32677

    47. Epa Pesticide Chemical Code 089001

    48. Nsc 135806

    49. Unii-0j6z13x3wo

    50. Ai3-03967

    51. Sulfato De Cinc

    52. Zinc(ii)sulfate

    53. Sulfato De Zinco

    54. Solfato Di Zinco

    55. Zinc (as Sulfate)

    56. Zinc(2+) Sulfate

    57. Mfcd00011302

    58. Zinc (as Sulphate)

    59. Zinc Sulphate Hydrate

    60. Zinci Sulfas Monohydrate

    61. Zinc Suflate Monohydrate

    62. Zinc Sulfate, Unspecified

    63. Zinc Sulfate [mi]

    64. Zinc Sulphate Nanoparticles

    65. Ec 231-793-3

    66. Zinc Sulfate [hsdb]

    67. Zinc Sulfate, Unspecified Form

    68. Chembl1200929

    69. Dtxsid2040315

    70. Akos025295737

    71. Zinc Sulfate, 100mm Aqueous Solution

    72. Db09322

    73. Q204954

    74. J-010404

    2.4 Create Date
    2004-09-16
    3 Chemical and Physical Properties
    Molecular Weight 161.4 g/mol
    Molecular Formula O4SZn
    Hydrogen Bond Donor Count0
    Hydrogen Bond Acceptor Count4
    Rotatable Bond Count0
    Exact Mass159.880871 g/mol
    Monoisotopic Mass159.880871 g/mol
    Topological Polar Surface Area88.6 Ų
    Heavy Atom Count6
    Formal Charge0
    Complexity62.2
    Isotope Atom Count0
    Defined Atom Stereocenter Count0
    Undefined Atom Stereocenter Count0
    Defined Bond Stereocenter Count0
    Undefined Bond Stereocenter Count0
    Covalently Bonded Unit Count2
    4 Drug and Medication Information
    4.1 Therapeutic Uses

    Mesh Heading: Astringent

    National Library of Medicine, SIS; ChemIDplus Record for Zinc Sulfate. (7733-02-0). Available from, as of April 17, 2006: https://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

    Dietary supplement ingredient in use before October 15, 1994 (Mineral and trace element) /Date of the Dietary Supplement Health and Education Act of 1994/..

    NNFA List of Dietary Supplement Ingredients In Use Before October 15, 1994. Available from, as of December 8, 2006: https://www.fda.gov/ohrms/dockets/dockets/05p0305/05p-0305-cr00001-03-NNFA-List-vol1.pdf

    MEDICATION (VET): Zinc sulfate, USP, applied topically in 10% aqueous solution, is highly effective in treatment of foot rot in sheep.

    Booth, N.H., L.E. McDonald (eds.). Veterinary Pharmacology and Therapeutics. 5th ed. Ames, Iowa: Iowa State University Press, 1982., p. 670

    MEDICATION (VET): Useful antiseptic astringent for ophthalmic use as aqueous solution or ointment (0.25-0.5%). Spraying sheep with 0.25% solution after shearing reduced incidence of infected wounds. 1% solutions have been used on granular vaginitis lesions of cows, posthitis of rams, and make excellent detergent, odorless, antiseptic egg wash. ... As white lotion ... on bruised, inflamed, pruritic skin areas on cows and horses.

    Rossoff, I.S. Handbook of Veterinary Drugs. New York: Springer Publishing Company, 1974., p. 669

    For more Therapeutic Uses (Complete) data for ZINC SULFATE (26 total), please visit the HSDB record page.

    4.2 Drug Warning

    ... Zinc sulfate often is an effective /emetic/, but potential hemolytic and renal toxicity is too great to recommend use ... .

    American Medical Association, AMA Department of Drugs. AMA Drug Evaluations. 5th ed. Chicago: American Medical Association, 1983., p. 489

    Thiazide diuretics have been found to increase urinary zinc excretion. /Zinc supplements/

    Thomson/Micromedex. Drug Information for the Health Care Professional. Volume 1, Greenwood Village, CO. 2006.

    Large doses of zinc may inhibit copper absorption in the intestine; zinc supplements should be taken at least 2 hours after the administration of copper supplements. /Zinc supplements/

    Thomson/Micromedex. Drug Information for the Health Care Professional. Volume 1, Greenwood Village, CO. 2006.

    Patients using zinc sulfate ophthalmic solutions should be advised to discontinue the drug and consult a physician if ocular pain or visual changes occur, they experience continued ocular redness or irritation, or the condition worsens or persists for more than 3 days.

    McEvoy, G.K. (ed.). American Hospital Formulary Service. AHFS Drug Information. American Society of Health-System Pharmacists, Bethesda, MD. 2006., p. 2761

    For more Drug Warnings (Complete) data for ZINC SULFATE (15 total), please visit the HSDB record page.

    4.3 Drug Indication

    This medication is a mineral used to treat or prevent low levels of zinc alone and together with oral rehydration therapy (ORT). It is also used as a topical astringent. Zinc Sulfate Injection, USP is indicated for use as a supplement to intravenous solutions given for TPN.

    Zinc sulfate is a common zinc supplement in parenteral nutrition.

    5 Pharmacology and Biochemistry
    5.1 Pharmacology

    Zinc has been identified as a cofactor for over 70 different enzymes, including alkaline phosphatase, lactic dehydrogenase and both RNA and DNA polymerase. Zinc facilitates wound healing, helps maintain normal growth rates, normal skin hydration and the senses of taste and smell.

    5.2 MeSH Pharmacological Classification

    Astringents

    Agents, usually topical, that cause the contraction of tissues for the control of bleeding or secretions. (See all compounds classified as Astringents.)

    5.3 FDA Pharmacological Classification
    5.3.1 Pharmacological Classes
    Decreased Copper Ion Absorption [PE]; Copper Absorption Inhibitor [EPC]
    5.4 ATC Code

    A - Alimentary tract and metabolism

    A12 - Mineral supplements

    A12C - Other mineral supplements

    A12CB - Zinc

    A12CB01 - Zinc sulfate

    B - Blood and blood forming organs

    B05 - Blood substitutes and perfusion solutions

    B05X - I.v. solution additives

    B05XA - Electrolyte solutions

    B05XA18 - Zinc sulfate

    5.5 Absorption, Distribution and Excretion

    Absorption

    Approximately 20 to 30% of dietary zinc is absorbed, primarily from the duodenum and ileum. The amount absorbed is dependent on the bioavailability from food. Zinc is the most bioavailable from red meat and oysters. Phytates may impair absorption by chelation and formation of insoluble complexes at an alkaline pH. After absorption, zinc is bound in the intestine to the protein metallothionein. Endogenous zinc can be reabsorbed in the ileum and colon, creating an enteropancreatic circulation of zinc.

    Route of Elimination

    Primarily fecal (approximately 90%); to a lesser extent in the urine and in perspiration.

    Volume of Distribution

    After absorption zinc is bound to protein metallothionein in the intestines. Zinc is widely distributed throughout the body. It is primarily stored in RBCs, WBCs, muscles, bones, Skin, Kidneys, Liver, Pancreas, retina, and prostate.

    The pharmacokinetics of zinc sulfate were compared with those of a new zinc pantothenate, in rabbits. Each salt was administered to rabbits at a dosage of 3.3 uCi of zinc-65/kg of body weight. The measured pharmacokinetics of the two compounds responded to a two compartment open model. The urinary elimination of the two salts was similar, as was their localization in the skin and fur, but Zn pantothenate was retained by the liver to a lesser extent than was zinc sulfate (ZnSO4).

    PMID:6520772 Guillard O et al; J Pharm Sci 73 (11): 1642-3 (1984)

    Absorption: 20% to 30%. Protein binding: 99%. Elimination: Through small bowel excretion.

    Lelkin, J.B., Paloucek, F.P., Poisoning & Toxicology Compendium. LEXI-COMP Inc. & American Pharmaceutical Association, Hudson, OH 1998., p. 573

    In women in different trimesters of pregnancy, the oral administration of 200 mg zinc sulfate per day resulted in an increase of serum zinc levels from 109.7 to 205.4 mg/dL. In the control group, serum zinc levels declined from 113.0 mg/dL in the first trimester to 83.8 in the third trimester.

    Bingham, E.; Cohrssen, B.; Powell, C.H.; Patty's Toxicology Volumes 1-9 5th ed. John Wiley & Sons. New York, N.Y. (2001)., p. 2:267

    ...An absorption half-life of 0.4 hr /was reported/ when 45 mg Zn2+ as zinc sulfate was administered once in gelatine capsules to 10 healthy young men. Serum concentrations were measured frequently during a total investigation time of 8 hours. A mean maximum concentration of 8.2 umol Zn2+/L serum was found after 2.3 hours (tmax). There is evidence of an enteral recirculation, the first rebound effect appeared after 1.4 hours during the absorption phase before tmax was reached, and exhibited mean reabsorption rates of 70% of the dose given. The subsequent ones (max. of 5) appeared at regular intervals of 1.2 hours with a decrease of the quantity reabsorbed.

    European Chemicals Bureau; EU Risk Assessment Report- Zinc sulphate, Vol.46 p.31 (2004). Available from, as of June 29, 2006: https://esis.jrc.ec.europa.eu/

    For more Absorption, Distribution and Excretion (Complete) data for ZINC SULFATE (14 total), please visit the HSDB record page.

    5.6 Biological Half-Life

    3 hours

    Half-life: 3 hours

    Lelkin, J.B., Paloucek, F.P., Poisoning & Toxicology Compendium. LEXI-COMP Inc. & American Pharmaceutical Association, Hudson, OH 1998., p. 573

    5.7 Mechanism of Action

    Zinc inhibits cAMP-induced, chloride-dependent fluid secretion by inhibiting basolateral potassium (K) channels, in in-vitro studies with rat ileum. This study has also shown the specificity of Zn to cAMP-activated K channels, because zinc did not block the calcium (Ca)-mediated K channels. As this study was not performed in Zn-deficient animals, it provides evidence that Zn is probably effective in the absence of Zn deficiency. Zinc also improves the absorption of water and electrolytes, improves regeneration of the intestinal epithelium, increases the levels of brush border enzymes, and enhances the immune response, allowing for a better clearance of the pathogens.

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    19-Jan-2021
    27-Sep-2024
    KGS
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    Average Price (USD/KGS)

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    Quantity (KGS) & Unit rate (USD/KGS) over time

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    (KGS)    		 Average Price
    (USD/KGS)    		 Number of Transactions

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