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CAS 2923-28-6

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Chemistry

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Also known as: 2923-28-6, Silver triflate, Silver(i) trifluoromethanesulfonate, Agotf, Silver trifluoromethanesulphonate, Trifluoromethanesulfonic acid silver salt

Molecular Formula

CAgF₃O₃S

Molecular Weight

256.94 g/mol

InChI Key

QRUBYZBWAOOHSV-UHFFFAOYSA-M

FDA UNII

UK2MGY9YSF

Silver trifluoromethanesulfonate, or silver triflate, is the triflate salt of silver. It is used in inorganic and organometallic chemistry to replace halide anions or ligands. Silver is a metallic element with the chemical symbol Ag and atomic number 47. It occurs naturally in its pure, free form, as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite. (L808, L809, L833)

1 2D Structure

CAS 2923-28-6

2 Identification

2.1 Computed Descriptors

2.1.1 IUPAC Name

silver;trifluoromethanesulfonate

2.1.2 InChI

InChI=1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1

2.1.3 InChI Key

QRUBYZBWAOOHSV-UHFFFAOYSA-M

2.1.4 Canonical SMILES

C(F)(F)(F)S(=O)(=O)[O-].[Ag+]

2.2 Other Identifiers

2.2.1 UNII

UK2MGY9YSF

2.3 Synonyms

2.3.1 MeSH Synonyms

1. Agotf Cpd

2. Al(otf)3

3. Aluminum Triflate

4. As(otf)2

5. Cerium Triflate

6. Cu(otf)2

7. Cupric Trifluoromethanesulfonate

8. Eu(otf)3

9. In(otf)3

10. Indium Triflate

11. Mercury(ii) Trifluoromethanesulfonate

12. Samarium Triflate

13. Silver Triflate

14. Tfmsa Cpd

15. Triflic Acid

16. Trifluoromethanesulfonate

17. Trifluoromethanesulfonic Acid

18. Trifluoromethanesulfonic Acid, Aluminum Salt

19. Trifluoromethanesulfonic Acid, Barium Salt

20. Trifluoromethanesulfonic Acid, Cerium (+3) Salt

21. Trifluoromethanesulfonic Acid, Cupric Salt

22. Trifluoromethanesulfonic Acid, Indium Salt

23. Trifluoromethanesulfonic Acid, Lanthanum (+3) Salt

24. Trifluoromethanesulfonic Acid, Lithium Salt

25. Trifluoromethanesulfonic Acid, Samarium Salt

26. Trifluoromethanesulfonic Acid, Silver (+1) Salt

27. Trifluoromethanesulfonic Acid, Zinc Salt

28. Zinc Triflate

2.3.2 Depositor-Supplied Synonyms

1. 2923-28-6

2. Silver Triflate

3. Silver(i) Trifluoromethanesulfonate

4. Agotf

5. Silver Trifluoromethanesulphonate

6. Trifluoromethanesulfonic Acid Silver Salt

7. Methanesulfonic Acid, Trifluoro-, Silver(1+) Salt

8. Silver Trifluoromethylsulfonate

9. Uk2mgy9ysf

10. Mfcd00013226

11. Silver(i)trifluoromethanesulfonate

12. Silver(i) Trifluoromethanesulphonate

13. Silver(1+) Ion Trifluoromethanesulfonate

14. Methanesulfonic Acid, 1,1,1-trifluoro-, Silver(1+) Salt (1:1)

15. Nsc-225087

16. Silver(1+) Trifluoromethanesulfonate

17. Einecs 220-882-2

18. Tempo, Freeradical

19. Silver (i) Trifluoromethane Sulfonate

20. Silver-(i)-triflate

21. Nsc 225087

22. Unii-uk2mgy9ysf

23. Silver Trifluoromethansulfonate

24. Schembl117027

25. Silver Triflouromethanesulfonate

26. Silver,trifluoromethanesulfonate

27. Silver;trifluoromethanesulfonate

28. Silver Trifluoromethane Sulfonate

29. Silver Trifluoromethane-sulfonate

30. Dtxsid5062716

31. Silver Trifluoro-methanesulphonate

32. Silver() Trifluorometanesulfonate

33. Silver(i)trifluoromethanesulphonate

34. 3-(4-tert-butylbenzoyl)acrylicacid

35. Act09487

36. Amy11804

37. Trifluoromethylsulfonyloxysilver

38. Akos009087791

39. Gs-6786

40. Sc10937

41. Trifluormethanesulfonic Acid Silver Salt

42. Silver (trifluoromethyl)sulfonate

43. Silver Trifluoromethanesulfonate, >=99%

44. Db-009810

45. Cs-0035255

46. Ft-0634560

47. Silver Trifluoromethanesulfonate (agcf3so3)

48. T1331

49. En300-23844

50. Q8215055

51. Silver Trifluoromethanesulfonate, Purum, >=98.0% (ag)

52. Silver Trifluoromethanesulfonate, >=99.95% Trace Metals Basis

53. Silver Trifluoromethanesulfonate, Trace Metals Grade, 99.95%

54. 2923-28-6 Inverted Exclamation Mark Inverted Exclamation Mark

55. Silver Trifluoromethanesulfonate (99.95%-ag) (silver Triflate)

56. Silver Trifluoromethanesulfonate Inverted Exclamation Mark Inverted Exclamation Mark

2.4 Create Date

2005-07-19

3 Chemical and Physical Properties

Molecular Formula	CAgF₃O₃S
Molecular Weight	256.94 g/mol
Hydrogen Bond Donor Count	0
Hydrogen Bond Acceptor Count	6
Rotatable Bond Count	0
Exact Mass	g/mol
Monoisotopic Mass	g/mol
Topological Polar Surface Area	65.6
Heavy Atom Count	9
Formal Charge	0
Complexity	145
Isotope Atom Count	0
Defined Atom Stereocenter Count	0
Undefined Atom Stereocenter Count	0
Defined Bond Stereocenter Count	0
Undefined Bond Stereocenter Count	0
Covalently Bonded Unit Count	2

4 Pharmacology and Biochemistry

4.1 Metabolism/Metabolites

Silver and its compounds can be absorbed via inhalation, while silver compounds can also be absorbed orally and dermally. It distributes throughout the body in the blood, particularily to the liver. Insoluble silver salts are transformed into soluble silver sulfide albuminates, bind to amino or carboxyl groups in RNA, DNA, and proteins, or are reduced to metallic silver by ascorbic acid or catecholamines. Metallic silver is oxidized and may deposit in the tissues, causing arygria. Silver is eliminated primarily in the faeces. (L808)

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